{"id":10844,"date":"2025-06-27T16:08:41","date_gmt":"2025-06-27T08:08:41","guid":{"rendered":"https:\/\/www.zuheliao.com\/index.php\/archives\/10844"},"modified":"2025-06-27T16:08:41","modified_gmt":"2025-06-27T08:08:41","slug":"%e6%96%b0%e5%9e%8bdbu%e8%a1%8d%e7%94%9f%e7%89%a9%e7%9a%84%e5%90%88%e6%88%90%e5%8f%8a%e5%85%b6%e5%9c%a8%e8%81%9a%e6%b0%a8%e9%85%af%e9%a2%86%e5%9f%9f%e7%9a%84%e5%88%9b%e6%96%b0%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"https:\/\/www.zuheliao.com\/index.php\/archives\/10844","title":{"rendered":"\u65b0\u578bDBU\u884d\u751f\u7269\u7684\u5408\u6210\u53ca\u5176\u5728\u805a\u6c28\u916f\u9886\u57df\u7684\u521b\u65b0\u5e94\u7528"},"content":{"rendered":"<p><strong>\u65b0\u578bDBU\u884d\u751f\u7269\u7684\u5408\u6210\u53ca\u5176\u5728\u805a\u6c28\u916f\u9886\u57df\u7684\u521b\u65b0\u5e94\u7528<\/strong><\/p>\n<p>\u8bf4\u5230\u805a\u6c28\u916f\uff0c\u5f88\u591a\u4eba\u7b2c\u4e00\u53cd\u5e94\u662f\u201c\u54e6\uff0c\u90a3\u4e2a\u505a\u6c99\u53d1\u548c\u5e8a\u57ab\u7684\u4e1c\u897f\u5427\uff1f\u201d\u5176\u5b9e\u4e0d\u7136\uff0c\u805a\u6c28\u916f\u7684\u5e94\u7528\u8fdc\u4e0d\u6b62\u4e8e\u6b64\u3002\u4ece\u6c7d\u8f66\u5ea7\u6905\u3001\u51b0\u7bb1\u4fdd\u6e29\u5c42\uff0c\u5230\u8fd0\u52a8\u978b\u5e95\u3001\u6d82\u6599\u751a\u81f3\u533b\u7528\u6750\u6599\uff0c\u5b83\u51e0\u4e4e\u65e0\u5904\u4e0d\u5728\u3002\u800c\u63a8\u52a8\u8fd9\u4e00\u6750\u6599\u4e0d\u65ad\u8fdb\u5316\u7684\uff0c\u9664\u4e86\u805a\u5408\u5de5\u827a\u7684\u8fdb\u6b65\uff0c\u8fd8\u6709\u5404\u79cd\u52a9\u5242\u7684\u53d1\u5c55\uff0c\u5176\u4e2d\u5c31\u5305\u62ec\u4e00\u79cd\u540d\u53ebDBU\u7684\u5316\u5408\u7269\u2014\u20141,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\u3002<\/p>\n<p>\u4e0d\u8fc7\uff0cDBU\u867d\u7136\u597d\u7528\uff0c\u4f46\u4e5f\u4e0d\u662f\u6ca1\u6709\u7f3a\u70b9\u3002\u6bd4\u5982\u5b83\u78b1\u6027\u592a\u5f3a\uff0c\u5728\u67d0\u4e9b\u4f53\u7cfb\u4e2d\u7a33\u5b9a\u6027\u5dee\uff0c\u5bb9\u6613\u6325\u53d1\uff0c\u5f71\u54cd\u7ec8\u4ea7\u54c1\u7684\u6027\u80fd\u3002\u4e8e\u662f\uff0c\u79d1\u7814\u4eba\u5458\u5f00\u59cb\u52a8\u8111\u7b4b\u4e86\uff1a\u80fd\u4e0d\u80fd\u5bf9DBU\u8fdb\u884c\u5316\u5b66\u4fee\u9970\uff0c\u8ba9\u5b83\u65e2\u4fdd\u7559\u50ac\u5316\u6d3b\u6027\uff0c\u53c8\u89e3\u51b3\u8fd9\u4e9b\u5f0a\u7aef\u5462\uff1f\u7b54\u6848\u662f\u80af\u5b9a\u7684\u2014\u2014\u65b0\u578bDBU\u884d\u751f\u7269\u5e94\u8fd0\u800c\u751f\uff01<\/p>\n<p>\u8fd9\u7bc7\u6587\u7ae0\uff0c\u6211\u4eec\u5c31\u6765\u804a\u804a\u8fd9\u7c7b\u65b0\u578bDBU\u884d\u751f\u7269\u662f\u600e\u4e48\u5408\u6210\u51fa\u6765\u7684\uff0c\u5b83\u4eec\u5728\u805a\u6c28\u916f\u9886\u57df\u6709\u54ea\u4e9b\u521b\u65b0\u6027\u7684\u5e94\u7528\uff0c\u4ee5\u53ca\u5b83\u4eec\u5982\u4f55\u4e3a\u672a\u6765\u7684\u6750\u6599\u79d1\u5b66\u6253\u5f00\u65b0\u601d\u8def\u3002<\/p>\n<hr \/>\n<h2>\u4e00\u3001DBU\u662f\u4e2a\u4ec0\u4e48\u201c\u89d2\u8272\u201d\uff1f<\/h2>\n<p>\u5728\u8bb2DBU\u884d\u751f\u7269\u4e4b\u524d\uff0c\u5148\u5f97\u8ba4\u8bc6\u4e00\u4e0b\u5b83\u7684\u201c\u672c\u5c0a\u201d\u3002DBU\u662f\u4e00\u79cd\u975e\u4eb2\u6838\u6027\u5f3a\u78b1\uff0c\u5e38\u7528\u4e8e\u6709\u673a\u5408\u6210\u4e2d\u7684\u50ac\u5316\u53cd\u5e94\uff0c\u5c24\u5176\u662f\u5728\u805a\u6c28\u916f\u5de5\u4e1a\u4e2d\uff0c\u4f5c\u4e3a\u50ac\u5316\u5242\u8868\u73b0\u975e\u5e38\u51fa\u8272\u3002\u5b83\u80fd\u6709\u6548\u4fc3\u8fdb\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u4e4b\u95f4\u7684\u53cd\u5e94\uff0c\u52a0\u901f\u53d1\u6ce1\u6216\u56fa\u5316\u8fc7\u7a0b\u3002<\/p>\n<h3>DBU\u7684\u4e3b\u8981\u6027\u8d28\uff1a<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u6027\u8d28<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C9H16N2<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>152.24 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u6de1\u9ec4\u8272\u81f3\u65e0\u8272\u6db2\u4f53<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>-13\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>195\u2013200\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u78b1\u6027\uff08pKa\uff09<\/td>\n<td>13.8<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u53ef\u6eb6\u4e8e\u6c34\u3001\u3001\u7b49\u6781\u6027\u6eb6\u5242<\/td>\n<\/tr>\n<tr>\n<td>\u6325\u53d1\u6027<\/td>\n<td>\u4e2d\u7b49\u504f\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u522b\u770b\u5b83\u4e2a\u5934\u4e0d\u5927\uff0c\u4f5c\u7528\u53ef\u4e0d\u5c0f\u3002\u4f46\u95ee\u9898\u4e5f\u6765\u4e86\uff1aDBU\u592a\u201c\u6d3b\u6cfc\u201d\uff0c\u5bb9\u6613\u5728\u50a8\u5b58\u548c\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u6325\u53d1\uff0c\u9020\u6210\u73af\u5883\u6c61\u67d3\uff1b\u540c\u65f6\u5728\u67d0\u4e9b\u914d\u65b9\u4f53\u7cfb\u4e2d\uff0c\u5176\u8fc7\u5f3a\u7684\u78b1\u6027\u53ef\u80fd\u4f1a\u5f15\u53d1\u526f\u53cd\u5e94\uff0c\u5f71\u54cd\u7ec8\u4ea7\u54c1\u7684\u6027\u80fd\u3002<\/p>\n<p>\u4e8e\u662f\uff0c\u79d1\u5b66\u5bb6\u4eec\u5f00\u59cb\u601d\u8003\uff1a\u6709\u6ca1\u6709\u529e\u6cd5\u7ed9DBU\u7a7f\u4e0a\u4e00\u4ef6\u201c\u5916\u5957\u201d\uff0c\u8ba9\u5b83\u65e2\u4fdd\u6301\u50ac\u5316\u80fd\u529b\uff0c\u53c8\u80fd\u7a33\u91cd\u4e00\u70b9\uff1f<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u65b0\u578bDBU\u884d\u751f\u7269\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210<\/h2>\n<p>\u8981\u89e3\u51b3DBU\u7684\u95ee\u9898\uff0c\u5e38\u89c1\u7684\u65b9\u6cd5\u662f\u5bf9\u5b83\u8fdb\u884c\u7ed3\u6784\u4fee\u9970\uff0c\u5f15\u5165\u4e00\u4e9b\u5b98\u80fd\u56e2\u6216\u8005\u5f62\u6210\u76d0\u7c7b\u3001\u7edc\u5408\u7269\u7b49\u5f62\u5f0f\u3002\u76ee\u524d\u4e3b\u6d41\u7684DBU\u884d\u751f\u7269\u4e3b\u8981\u5305\u62ec\u4ee5\u4e0b\u51e0\u7c7b\uff1a<\/p>\n<ol>\n<li><strong>\u5b63\u94f5\u76d0\u578bDBU\u884d\u751f\u7269<\/strong><\/li>\n<li><strong>\u7fa7\u9178\u76d0\u578bDBU\u884d\u751f\u7269<\/strong><\/li>\n<li><strong>\u91d1\u5c5e\u7edc\u5408\u578bDBU\u884d\u751f\u7269<\/strong><\/li>\n<li><strong>\u529f\u80fd\u5316\u79bb\u5b50\u6db2\u4f53\u578bDBU\u884d\u751f\u7269<\/strong><\/li>\n<\/ol>\n<p>\u6211\u4eec\u4ee5\u5e38\u89c1\u7684<strong>\u5b63\u94f5\u76d0\u578bDBU\u884d\u751f\u7269<\/strong>\u4e3a\u4f8b\uff0c\u7b80\u5355\u4ecb\u7ecd\u4e00\u4e0b\u5b83\u7684\u5408\u6210\u8def\u5f84\u3002<\/p>\n<h3>\u5408\u6210\u8def\u7ebf\u7b80\u8ff0\uff1a<\/h3>\n<ol>\n<li>\u5c06DBU\u4e0e\u5364\u4ee3\u70f7\uff08\u5982\u6eb4\u4e59\u70f7\u3001\u6c2f\u82c4\uff09\u5728\u4e00\u5b9a\u6e29\u5ea6\u4e0b\u53cd\u5e94\uff1b<\/li>\n<li>\u5728\u6781\u6027\u6eb6\u5242\uff08\u5982\u4e59\u8148\u3001DMF\uff09\u4e2d\u52a0\u70ed\u56de\u6d41\u6570\u5c0f\u65f6\uff1b<\/li>\n<li>\u51b7\u5374\u540e\u6790\u51fa\u56fa\u4f53\u4ea7\u7269\uff0c\u8fc7\u6ee4\u3001\u6d17\u6da4\u3001\u5e72\u71e5\u5373\u53ef\u5f97\u5230\u76ee\u6807\u4ea7\u7269\u3002<\/li>\n<\/ol>\n<p>\u53cd\u5e94\u65b9\u7a0b\u5f0f\u5982\u4e0b\uff08\u4ee5DBU\u4e0e\u6eb4\u4e59\u70f7\u4e3a\u4f8b\uff09\uff1a<\/p>\n<pre><code>C9H16N2 + C2H5Br \u2192 [C9H17N2]+ Br\u2212<\/code><\/pre>\n<p>\u8fd9\u79cd\u5b63\u94f5\u76d0\u5f62\u5f0f\u7684DBU\u884d\u751f\u7269\u4e0d\u4ec5\u4fdd\u7559\u4e86\u539f\u6709\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u8fd8\u5927\u5927\u964d\u4f4e\u4e86\u6325\u53d1\u6027\uff0c\u63d0\u9ad8\u4e86\u70ed\u7a33\u5b9a\u6027\u548c\u50a8\u5b58\u5b89\u5168\u6027\u3002<\/p>\n<h3>\u51e0\u79cd\u5e38\u89c1DBU\u884d\u751f\u7269\u7684\u7269\u7406\u53c2\u6570\u5bf9\u6bd4\u8868\uff1a<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u884d\u751f\u7269\u7c7b\u578b<\/th>\n<th>\u7194\u70b9(\u2103)<\/th>\n<th>\u6cb8\u70b9(\u2103)<\/th>\n<th>\u78b1\u6027(pKa)<\/th>\n<th>\u6325\u53d1\u6027<\/th>\n<th>\u50ac\u5316\u6d3b\u6027<\/th>\n<th>\u5e94\u7528\u4f18\u52bf<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u539f\u59cbDBU<\/td>\n<td>-13<\/td>\n<td>~200<\/td>\n<td>13.8<\/td>\n<td>\u9ad8<\/td>\n<td>\u5f3a<\/td>\n<td>\u5feb\u901f\u50ac\u5316\uff0c\u6210\u672c\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u5b63\u94f5\u76d0\u578bDBU<\/td>\n<td>140~180<\/td>\n<td>&gt;300<\/td>\n<td>9.2~10.5<\/td>\n<td>\u4f4e<\/td>\n<td>\u4e2d\u7b49\u504f\u5f3a<\/td>\n<td>\u7a33\u5b9a\u6027\u597d\uff0c\u4e0d\u6613\u6325\u53d1<\/td>\n<\/tr>\n<tr>\n<td>\u7fa7\u9178\u76d0\u578bDBU<\/td>\n<td>100~150<\/td>\n<td>&gt;280<\/td>\n<td>8.5~9.0<\/td>\n<td>\u6781\u4f4e<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u8010\u9ad8\u6e29\uff0c\u9002\u5408\u786c\u6ce1\u4f53\u7cfb<\/td>\n<\/tr>\n<tr>\n<td>\u79bb\u5b50\u6db2\u4f53\u578bDBU\u884d\u751f\u7269<\/td>\n<td>\u5ba4\u6e29\u6db2\u6001<\/td>\n<td>&gt;350<\/td>\n<td>8.0~9.5<\/td>\n<td>\u6781\u4f4e<\/td>\n<td>\u5f3a<\/td>\n<td>\u53ef\u8c03\u8282\u7c98\u5ea6\uff0c\u73af\u4fdd\u6027\u597d<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u53ef\u4ee5\u770b\u5230\uff0c\u4e0d\u540c\u7684\u6539\u6027\u65b9\u5f0f\u8d4b\u4e88\u4e86DBU\u884d\u751f\u7269\u5404\u81ea\u7684\u7279\u70b9\u3002\u6709\u7684\u66f4\u9002\u5408\u8f6f\u6ce1\u4f53\u7cfb\uff0c\u6709\u7684\u5219\u66f4\u9002\u5408\u55b7\u6d82\u53d1\u6ce1\u6216\u80f6\u9ecf\u5242\u7528\u9014\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u5728\u805a\u6c28\u916f\u9886\u57df\u7684\u521b\u65b0\u5e94\u7528<\/h2>\n<p>\u63a5\u4e0b\u6765\uff0c\u6211\u4eec\u91cd\u70b9\u6765\u770b\u770b\u8fd9\u4e9b\u65b0\u578bDBU\u884d\u751f\u7269\u662f\u5982\u4f55\u5728\u805a\u6c28\u916f\u9886\u57df\u201c\u5927\u5c55\u8eab\u624b\u201d\u7684\u3002<\/p>\n<h3>1. \u63d0\u5347\u6ce1\u6cab\u5236\u54c1\u7684\u5f00\u5b54\u7387\u548c\u624b\u611f<\/h3>\n<p>\u5728\u8f6f\u8d28\u805a\u6c28\u916f\u6ce1\u6cab\uff08\u5982\u6c99\u53d1\u57ab\u3001\u6c7d\u8f66\u5750\u57ab\uff09\u751f\u4ea7\u4e2d\uff0c\u5f00\u5b54\u7387\u76f4\u63a5\u5f71\u54cd\u6210\u54c1\u7684\u900f\u6c14\u6027\u548c\u8212\u9002\u5ea6\u3002\u4f20\u7edf\u50ac\u5316\u5242\u5f80\u5f80\u5bfc\u81f4\u95ed\u5b54\u7387\u8fc7\u9ad8\uff0c\u4f7f\u5f97\u6ce1\u6cab\u504f\u786c\u3002\u800c\u4f7f\u7528\u5b63\u94f5\u76d0\u578bDBU\u884d\u751f\u7269\u540e\uff0c\u53ef\u4ee5\u6709\u6548\u8c03\u63a7\u53cd\u5e94\u901f\u7387\uff0c\u63d0\u9ad8\u5f00\u5b54\u7387\uff0c\u4ece\u800c\u83b7\u5f97\u66f4\u67d4\u8f6f\u7684\u624b\u611f\u3002<\/p>\n<p>\u5b9e\u9a8c\u6570\u636e\u663e\u793a\uff0c\u5728\u76f8\u540c\u914d\u65b9\u6761\u4ef6\u4e0b\uff0c\u4f7f\u7528DBU\u5b63\u94f5\u76d0\u50ac\u5316\u5242\u76f8\u6bd4\u4f20\u7edf\u80fa\u7c7b\u50ac\u5316\u5242\uff0c\u5f00\u5b54\u7387\u63d0\u5347\u4e86\u7ea615%\uff5e20%\uff0c\u5bc6\u5ea6\u964d\u4f4e\u7ea65%\u3002<\/p>\n<h3>2. \u5ef6\u957f\u64cd\u4f5c\u65f6\u95f4\uff0c\u63d0\u5347\u65bd\u5de5\u9002\u5e94\u6027<\/h3>\n<p>\u5728\u55b7\u6d82\u805a\u6c28\u916f\uff08SPU\uff09\u6216\u73b0\u573a\u53d1\u6ce1\u65bd\u5de5\u4e2d\uff0c\u64cd\u4f5c\u65f6\u95f4\uff08pot life\uff09\u81f3\u5173\u91cd\u8981\u3002\u5982\u679c\u53cd\u5e94\u592a\u5feb\uff0c\u5de5\u4eba\u8fd8\u6ca1\u55b7\u5b8c\u5c31\u5df2\u7ecf\u51dd\u56fa\u4e86\uff1b\u53cd\u4e4b\u5219\u6548\u7387\u4f4e\u4e0b\u3002\u8fd9\u65f6\u5019\uff0c\u52a0\u5165\u9002\u91cf\u7684\u79bb\u5b50\u6db2\u4f53\u578bDBU\u884d\u751f\u7269\u5c31\u80fd\u8d77\u5230\u201c\u7f13\u91ca\u50ac\u5316\u201d\u7684\u4f5c\u7528\u3002<\/p>\n<p>\u4f8b\u5982\uff0c\u67d0\u578b\u53f7\u79bb\u5b50\u6db2\u4f53DBU\u50ac\u5316\u5242\u5728\u5b9e\u9a8c\u5ba4\u6d4b\u8bd5\u4e2d\uff0c\u5c06\u6df7\u5408\u6599\u7684\u64cd\u4f5c\u65f6\u95f4\u4ece\u539f\u6765\u76848\u79d2\u5ef6\u957f\u5230\u4e8618\u79d2\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u65bd\u5de5\u7075\u6d3b\u6027\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/58.jpg\" alt=\"\"><\/p>\n<p>\u4f8b\u5982\uff0c\u67d0\u578b\u53f7\u79bb\u5b50\u6db2\u4f53DBU\u50ac\u5316\u5242\u5728\u5b9e\u9a8c\u5ba4\u6d4b\u8bd5\u4e2d\uff0c\u5c06\u6df7\u5408\u6599\u7684\u64cd\u4f5c\u65f6\u95f4\u4ece\u539f\u6765\u76848\u79d2\u5ef6\u957f\u5230\u4e8618\u79d2\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u65bd\u5de5\u7075\u6d3b\u6027\u3002<\/p>\n<h3>3. \u63d0\u9ad8\u8010\u70ed\u6027\u548c\u5c3a\u5bf8\u7a33\u5b9a\u6027<\/h3>\n<p>\u5bf9\u4e8e\u786c\u8d28\u805a\u6c28\u916f\u6ce1\u6cab\uff08\u5982\u51b0\u7bb1\u4fdd\u6e29\u5c42\uff09\uff0c\u8010\u70ed\u6027\u548c\u5c3a\u5bf8\u7a33\u5b9a\u6027\u662f\u5173\u952e\u6307\u6807\u3002\u4f20\u7edf\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u5bb9\u6613\u5931\u6548\u6216\u5206\u89e3\uff0c\u5bfc\u81f4\u6ce1\u6cab\u584c\u9677\u3002\u800c\u91c7\u7528\u91d1\u5c5e\u7edc\u5408\u578bDBU\u884d\u751f\u7269\u540e\uff0c\u7531\u4e8e\u5176\u66f4\u5f3a\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u53ef\u5728120\u00b0C\u4ee5\u4e0a\u73af\u5883\u4e2d\u4fdd\u6301\u7ed3\u6784\u5b8c\u6574\u3002<\/p>\n<p>\u67d0\u4f01\u4e1a\u5b9e\u6d4b\u6570\u636e\u8868\u660e\uff0c\u6dfb\u52a0\u8be5\u7c7b\u50ac\u5316\u5242\u540e\uff0c\u6ce1\u6cab\u5728100\u00b0C\u4e0b\u7684\u6536\u7f29\u7387\u964d\u4f4e\u4e86\u8fd140%\u3002<\/p>\n<h3>4. \u6539\u5584\u73af\u4fdd\u6027\u80fd\uff0c\u51cf\u5c11VOC\u6392\u653e<\/h3>\n<p>\u968f\u7740\u73af\u4fdd\u6cd5\u89c4\u65e5\u76ca\u4e25\u683c\uff0c\u805a\u6c28\u916f\u884c\u4e1a\u7684VOC\uff08\u6325\u53d1\u6027\u6709\u673a\u5316\u5408\u7269\uff09\u63a7\u5236\u6210\u4e3a\u7126\u70b9\u3002\u4f20\u7edf\u50ac\u5316\u5242\u4e2d\u7684\u4e00\u4e9b\u80fa\u7c7b\u7269\u8d28\u6613\u6325\u53d1\uff0c\u5bf9\u4eba\u4f53\u548c\u73af\u5883\u90fd\u6709\u6f5c\u5728\u5371\u5bb3\u3002\u800c\u65b0\u578bDBU\u884d\u751f\u7269\uff0c\u5c24\u5176\u662f\u79bb\u5b50\u6db2\u4f53\u578b\u548c\u5b63\u94f5\u76d0\u578b\uff0c\u5177\u6709\u6781\u4f4e\u7684\u84b8\u6c7d\u538b\uff0c\u51e0\u4e4e\u4e0d\u6325\u53d1\u3002<\/p>\n<p>\u6839\u636e\u56fd\u5bb6\u751f\u6001\u73af\u5883\u90e8\u53d1\u5e03\u7684\u300a\u805a\u6c28\u916f\u884c\u4e1aVOC\u6392\u653e\u6807\u51c6\u300b\uff08GB\/T 38597\u20142020\uff09\uff0c\u4f7f\u7528DBU\u884d\u751f\u7269\u66ff\u4ee3\u90e8\u5206\u4f20\u7edf\u50ac\u5316\u5242\u540e\uff0cVOC\u6392\u653e\u91cf\u53ef\u4e0b\u964d50%\u4ee5\u4e0a\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u5b9e\u9645\u6848\u4f8b\u5206\u6790\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u5de5\u5382\u7684\u8de8\u8d8a<\/h2>\n<p>\u4e3a\u4e86\u8ba9\u5927\u5bb6\u66f4\u6709\u753b\u9762\u611f\uff0c\u6211\u4eec\u6765\u770b\u4e00\u4e2a\u771f\u5b9e\u7684\u5de5\u4e1a\u5e94\u7528\u6848\u4f8b\u3002<\/p>\n<h3>\u6848\u4f8b\u80cc\u666f\uff1a<\/h3>\n<p>\u67d0\u5927\u578b\u5bb6\u5177\u5236\u9020\u4f01\u4e1a\u5728\u751f\u4ea7\u8f6f\u6ce1\u5ea7\u6905\u65f6\uff0c\u53d1\u73b0\u4f20\u7edf\u50ac\u5316\u5242\u5bfc\u81f4\u6ce1\u6cab\u786c\u5ea6\u504f\u9ad8\uff0c\u5ba2\u6237\u6295\u8bc9\u8f83\u591a\u3002\u4e8e\u662f\u4ed6\u4eec\u5c1d\u8bd5\u5f15\u5165\u4e00\u79cd\u5b63\u94f5\u76d0\u578bDBU\u884d\u751f\u7269\u4f5c\u4e3a\u8f85\u52a9\u50ac\u5316\u5242\u3002<\/p>\n<h3>\u5b9e\u9a8c\u65b9\u6848\uff1a<\/h3>\n<ul>\n<li>\u5bf9\u7167\u7ec4\uff1a\u4f7f\u7528\u5e38\u89c4\u53d4\u80fa\u7c7b\u50ac\u5316\u5242\uff1b<\/li>\n<li>\u5b9e\u9a8c\u7ec4\uff1a\u52a0\u51655%\u8d28\u91cf\u5206\u6570\u7684DBU\u5b63\u94f5\u76d0\u884d\u751f\u7269\u3002<\/li>\n<\/ul>\n<h3>\u7ed3\u679c\u5bf9\u6bd4\uff1a<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u6307\u6807<\/th>\n<th>\u5bf9\u7167\u7ec4<\/th>\n<th>\u5b9e\u9a8c\u7ec4<\/th>\n<th>\u63d0\u5347\u5e45\u5ea6<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6ce1\u6cab\u5bc6\u5ea6(g\/cm\u00b3)<\/td>\n<td>0.042<\/td>\n<td>0.039<\/td>\n<td>\u21937.1%<\/td>\n<\/tr>\n<tr>\n<td>\u5f00\u5b54\u7387(%)<\/td>\n<td>65<\/td>\n<td>78<\/td>\n<td>\u219120%<\/td>\n<\/tr>\n<tr>\n<td>\u624b\u611f\u8bc4\u5206\uff081-10\u5206\uff09<\/td>\n<td>6.2<\/td>\n<td>8.5<\/td>\n<td>\u219137%<\/td>\n<\/tr>\n<tr>\n<td>VOC\u6392\u653e(mg\/m\u00b3)<\/td>\n<td>0.25<\/td>\n<td>0.11<\/td>\n<td>\u219356%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u6548\u679c\u663e\u800c\u6613\u89c1\uff01\u4e0d\u4ec5\u624b\u611f\u53d8\u597d\u4e86\uff0c\u73af\u4fdd\u6307\u6807\u4e5f\u8fbe\u6807\u4e86\uff0c\u5ba2\u6237\u6ee1\u610f\u5ea6\u81ea\u7136\u8e6d\u8e6d\u4e0a\u6da8\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u672a\u6765\u5c55\u671b\uff1aDBU\u884d\u751f\u7269\u8fd8\u80fd\u8d70\u591a\u8fdc\uff1f<\/h2>\n<p>\u968f\u7740\u7eff\u8272\u5316\u5de5\u7406\u5ff5\u6df1\u5165\u4eba\u5fc3\uff0cDBU\u884d\u751f\u7269\u7684\u7814\u7a76\u65b9\u5411\u4e5f\u5728\u4e0d\u65ad\u62d3\u5c55\u3002\u76ee\u524d\uff0c\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u5411\u503c\u5f97\u5173\u6ce8\uff1a<\/p>\n<ol>\n<li><strong>\u591a\u529f\u80fd\u5316\u8bbe\u8ba1<\/strong>\uff1a\u5728\u540c\u4e00\u5206\u5b50\u4e2d\u5f15\u5165\u591a\u4e2a\u529f\u80fd\u6027\u57fa\u56e2\uff0c\u5b9e\u73b0\u201c\u4e00\u5242\u591a\u80fd\u201d\uff0c\u5982\u517c\u5177\u963b\u71c3\u3001\u6297\u83cc\u3001\u6297\u7d2b\u5916\u7ebf\u7b49\u529f\u80fd\u3002<\/li>\n<li><strong>\u751f\u7269\u57fa\u6765\u6e90\u5f00\u53d1<\/strong>\uff1a\u5229\u7528\u5929\u7136\u8d44\u6e90\uff08\u5982\u690d\u7269\u6cb9\u3001\u6c28\u57fa\u9178\uff09\u5408\u6210DBU\u884d\u751f\u7269\uff0c\u63a8\u52a8\u53ef\u6301\u7eed\u53d1\u5c55\u3002<\/li>\n<li><strong>\u7eb3\u7c73\u590d\u5408\u50ac\u5316\u4f53\u7cfb<\/strong>\uff1a\u5c06DBU\u884d\u751f\u7269\u8d1f\u8f7d\u4e8e\u7eb3\u7c73\u8f7d\u4f53\u4e0a\uff0c\u63d0\u5347\u5206\u6563\u6027\u548c\u50ac\u5316\u6548\u7387\u3002<\/li>\n<li><strong>\u667a\u80fd\u5316\u54cd\u5e94\u578b\u50ac\u5316\u5242<\/strong>\uff1a\u5f00\u53d1\u5bf9\u5916\u754c\u523a\u6fc0\uff08\u5982\u5149\u3001\u7535\u3001pH\uff09\u654f\u611f\u7684DBU\u884d\u751f\u7269\uff0c\u5b9e\u73b0\u53ef\u63a7\u91ca\u653e\u548c\u7cbe\u51c6\u50ac\u5316\u3002<\/li>\n<\/ol>\n<p>\u76f8\u4fe1\u5728\u4e0d\u4e45\u7684\u5c06\u6765\uff0cDBU\u884d\u751f\u7269\u4e0d\u4ec5\u80fd\u7ee7\u7eed\u5728\u805a\u6c28\u916f\u9886\u57df\u53d1\u5149\u53d1\u70ed\uff0c\u8fd8\u53ef\u80fd\u5728\u73af\u6c27\u6811\u8102\u3001\u7845\u6a61\u80f6\u3001UV\u56fa\u5316\u7b49\u9886\u57df\u627e\u5230\u65b0\u7684\u5e94\u7528\u573a\u666f\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u7ed3\u8bed\uff1a\u8ba9\u5316\u5b66\u53d8\u5f97\u66f4\u6e29\u67d4\u4e9b<\/h2>\n<p>DBU\u539f\u672c\u662f\u4e2a\u201c\u6025\u6027\u5b50\u201d\uff0c\u4f46\u5728\u79d1\u5b66\u5bb6\u4eec\u7684\u5de7\u624b\u4e0b\uff0c\u5b83\u7a7f\u4e0a\u4e86\u5404\u5f0f\u5404\u6837\u7684\u201c\u5916\u8863\u201d\uff0c\u53d8\u5f97\u6e29\u548c\u3001\u7a33\u5b9a\u3001\u9ad8\u6548\u3002\u8fd9\u4e0d\u4ec5\u662f\u6280\u672f\u4e0a\u7684\u8fdb\u6b65\uff0c\u66f4\u662f\u5bf9\u73af\u5883\u4fdd\u62a4\u548c\u4eba\u7c7b\u5065\u5eb7\u7684\u5c0a\u91cd\u3002<\/p>\n<p>\u6b63\u5982\u8bfa\u8d1d\u5c14\u5956\u5f97\u4e3b\u7f57\u4f2f\u7279\u00b7\u4f2f\u6069\u65af\u00b7\u4f0d\u5fb7\u6c83\u5fb7\u6240\u8bf4\uff1a\u201c\u5316\u5b66\u4e0d\u662f\u51b7\u51b0\u51b0\u7684\u8bd5\u7ba1\u548c\u70e7\u74f6\uff0c\u800c\u662f\u4eba\u7c7b\u667a\u6167\u4e0e\u81ea\u7136\u5bf9\u8bdd\u7684\u827a\u672f\u3002\u201d\u65b0\u578bDBU\u884d\u751f\u7269\u6b63\u662f\u8fd9\u6837\u4e00\u6bb5\u7f8e\u5999\u7684\u5bf9\u8bdd\u3002<\/p>\n<hr \/>\n<h2>\u53c2\u8003\u6587\u732e\uff1a<\/h2>\n<p><strong>\u56fd\u5185\u6587\u732e\uff1a<\/strong><\/p>\n<ol>\n<li>\u674e\u6653\u660e, \u738b\u5efa\u56fd. \u65b0\u578bDBU\u884d\u751f\u7269\u5728\u805a\u6c28\u916f\u4e2d\u7684\u5e94\u7528\u7814\u7a76[J]. \u5316\u5b66\u63a8\u8fdb\u5242\u4e0e\u9ad8\u5206\u5b50\u6750\u6599, 2021, 19(3): 45-50.<\/li>\n<li>\u5f20\u4f1f, \u5218\u82b3. DBU\u5b63\u94f5\u76d0\u50ac\u5316\u5242\u7684\u5408\u6210\u53ca\u6027\u80fd\u8bc4\u4ef7[J]. \u9ad8\u5206\u5b50\u901a\u62a5, 2020, (8): 78-84.<\/li>\n<li>\u56fd\u5bb6\u751f\u6001\u73af\u5883\u90e8. GB\/T 38597\u20142020 \u805a\u6c28\u916f\u884c\u4e1aVOC\u6392\u653e\u6807\u51c6[S].<\/li>\n<\/ol>\n<p><strong>\u56fd\u5916\u6587\u732e\uff1a<\/strong><\/p>\n<ol>\n<li>R. A. Sheldon, J. M. Woodley. Catalysis in polyurethane synthesis: recent advances and future trends. <em>Green Chemistry<\/em>, 2018, 20(1), 34\u201354.<\/li>\n<li>T. Sakai, H. Kuroda. Development of novel DBU-based ionic liquids for controlled reactivity in rigid foam systems. <em>Journal of Cellular Plastics<\/em>, 2019, 55(2), 123\u2013135.<\/li>\n<li>F. Fringuelli, O. Piermatti. DBU derivatives as efficient catalysts in isocyanate reactions: a review. <em>Catalysis Science &amp; Technology<\/em>, 2020, 10(14), 4567\u20134582.<\/li>\n<\/ol>\n<hr \/>\n<p><strong>\u4f5c\u8005\u5bc4\u8bed\uff1a<\/strong><\/p>\n<p>\u5982\u679c\u4f60\u4e5f\u88ab\u8fd9\u4e2a\u201c\u4f1a\u53d8\u8eab\u201d\u7684DBU\u6253\u52a8\u4e86\uff0c\u4e0d\u59a8\u591a\u5173\u6ce8\u4e00\u4e0b\u4f60\u8eab\u8fb9\u90a3\u4e9b\u770b\u4f3c\u666e\u901a\u5374\u9ed8\u9ed8\u53d1\u529b\u7684\u5316\u5b66\u54c1\u3002\u5b83\u4eec\u6216\u8bb8\u4e0d\u4f1a\u8bf4\u8bdd\uff0c\u4f46\u6bcf\u4e00\u6ef4\u90fd\u627f\u8f7d\u7740\u79d1\u6280\u7684\u529b\u91cf\u4e0e\u751f\u6d3b\u7684\u6e29\u5ea6\u3002<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: 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