{"id":10539,"date":"2025-06-24T14:41:36","date_gmt":"2025-06-24T06:41:36","guid":{"rendered":"https:\/\/www.zuheliao.com\/index.php\/archives\/10539"},"modified":"2025-06-24T14:41:36","modified_gmt":"2025-06-24T06:41:36","slug":"%e5%9b%9b%e7%94%b2%e5%9f%ba%e8%83%8d%e5%a6%82%e4%bd%95%e4%bd%9c%e4%b8%ba%e6%9c%89%e6%9c%ba%e5%90%88%e6%88%90%e4%b8%ad%e7%9a%84%e9%ab%98%e6%95%88%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"https:\/\/www.zuheliao.com\/index.php\/archives\/10539","title":{"rendered":"\u56db\u7532\u57fa\u80cd\u5982\u4f55\u4f5c\u4e3a\u6709\u673a\u5408\u6210\u4e2d\u7684\u9ad8\u6548\u50ac\u5316\u5242"},"content":{"rendered":"<h3>\u56db\u7532\u57fa\u80cd\uff1a\u6709\u673a\u5408\u6210\u4e2d\u7684\u201c\u50ac\u5316\u5242\u5c0f\u738b\u5b50\u201d<\/h3>\n<p>\u5728\u6709\u673a\u5408\u6210\u8fd9\u4e2a\u4e94\u5f69\u6591\u6593\u7684\u5316\u5b66\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u662f\u4e00\u7fa4\u9ed8\u9ed8\u65e0\u95fb\u5374\u4e0d\u53ef\u6216\u7f3a\u7684\u201c\u5e55\u540e\u82f1\u96c4\u201d\u3002\u5b83\u4eec\u4e0d\u55a7\u54d7\u3001\u4e0d\u5f20\u626c\uff0c\u5374\u603b\u80fd\u5728\u5173\u952e\u65f6\u523b\u633a\u8eab\u800c\u51fa\uff0c\u8ba9\u53cd\u5e94\u4e8b\u534a\u529f\u500d\u3002\u800c\u5728\u8fd9\u4e9b\u50ac\u5316\u5242\u4e2d\uff0c\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine\uff0c\u7b80\u79f0TMG\uff09\u53ef\u4ee5\u8bf4\u662f\u4e00\u4f4d\u4f4e\u8c03\u5374\u9ad8\u6548\u7684\u201c\u5b9e\u529b\u6d3e\u9009\u624b\u201d\uff0c\u5b83\u4e0d\u4ec5\u5728\u4f17\u591a\u6709\u673a\u53cd\u5e94\u4e2d\u5927\u653e\u5f02\u5f69\uff0c\u8fd8\u56e0\u5176\u72ec\u7279\u7684\u7ed3\u6784\u548c\u6027\u80fd\u6210\u4e3a\u79d1\u7814\u5de5\u4f5c\u8005\u5fc3\u4e2d\u7684\u201c\u5b9d\u85cf\u5206\u5b50\u201d\u3002<\/p>\n<hr \/>\n<h2>\u4e00\u3001\u4ece\u5934\u8bf4\u8d77\uff1a\u4ec0\u4e48\u662f\u56db\u7532\u57fa\u80cd\uff1f<\/h2>\n<p>\u56db\u7532\u57fa\u80cd\uff0c\u5316\u5b66\u5f0f\u4e3aC\u2085H\u2081\u2083N\u2083\uff0c\u662f\u4e00\u79cd\u5f3a\u78b1\u6027\u6709\u673a\u5316\u5408\u7269\u3002\u5b83\u7684\u7ed3\u6784\u975e\u5e38\u6709\u8da3\u2014\u2014\u4e2d\u95f4\u662f\u4e00\u4e2a\u80cd\u57fa\u56e2\uff08\u2013N=C(NH\u2082)NH\u2013\uff09\uff0c\u5468\u56f4\u88ab\u56db\u4e2a\u7532\u57fa\u5305\u56f4\uff0c\u5f62\u6210\u4e00\u4e2a\u7c7b\u4f3c\u201c\u7687\u51a0\u201d\u822c\u7684\u7acb\u4f53\u6784\u578b\u3002\u8fd9\u79cd\u7ed3\u6784\u8d4b\u4e88\u4e86\u5b83\u6781\u5f3a\u7684\u78b1\u6027\u548c\u826f\u597d\u7684\u4eb2\u6838\u6027\uff0c\u4f7f\u5176\u5728\u591a\u79cd\u6709\u673a\u53cd\u5e94\u4e2d\u90fd\u80fd\u626e\u6f14\u91cd\u8981\u89d2\u8272\u3002<\/p>\n<h3>\u57fa\u672c\u53c2\u6570\u4e00\u89c8\u8868\uff1a<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u5c5e\u6027<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C\u2085H\u2081\u2083N\u2083<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>115.17 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u65e0\u8272\u6db2\u4f53\u6216\u767d\u8272\u56fa\u4f53\uff08\u53d6\u51b3\u4e8e\u6e29\u5ea6\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>2 \u2013 4\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>150 \u2013 155\u00b0C\uff08\u5e38\u538b\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>0.93 g\/cm\u00b3<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u6613\u6eb6\u4e8e\u6c34\u3001\u3001\u4e59\u8148\u7b49\u6781\u6027\u6eb6\u5242<\/td>\n<\/tr>\n<tr>\n<td>pKa<\/td>\n<td>\u7ea612.6\uff08\u6c34\u4e2d\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u6c14\u5473<\/td>\n<td>\u5f31\u6c28\u5473<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u522b\u770b\u5b83\u4e2a\u5934\u4e0d\u5927\uff0c\u4f46\u5b83\u53ef\u662f\u4e2a\u201c\u78b1\u754c\u9ad8\u624b\u201d\uff0c\u5176\u78b1\u6027\u5f3a\u4e8e\u5e38\u89c1\u7684\u4e09\u4e59\u80fa\uff08TEA\uff09\u3001\u5421\u5576\u7b49\u7ecf\u5178\u6709\u673a\u78b1\uff0c\u751a\u81f3\u80fd\u5ab2\u7f8e\u6c22\u6c27\u5316\u94a0\u8fd9\u6837\u7684\u65e0\u673a\u5f3a\u78b1\u3002\u4f46\u4e0d\u540c\u4e8e\u540e\u8005\u7684\u662f\uff0c\u5b83\u5177\u6709\u66f4\u597d\u7684\u6eb6\u89e3\u6027\u548c\u66f4\u4f4e\u7684\u8150\u8680\u6027\uff0c\u5728\u6709\u673a\u76f8\u4e2d\u8868\u73b0\u5f97\u66f4\u6e29\u548c\u4e5f\u66f4\u6709\u6548\u3002<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u4e3a\u4f55\u9009\u5b83\uff1f\u56db\u7532\u57fa\u80cd\u7684\u4f18\u52bf\u4f55\u5728\uff1f<\/h2>\n<p>\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0c\u9009\u62e9\u5408\u9002\u7684\u50ac\u5316\u5242\u5f80\u5f80\u51b3\u5b9a\u4e86\u53cd\u5e94\u6210\u8d25\u3002\u800c\u56db\u7532\u57fa\u80cd\u4e4b\u6240\u4ee5\u53d7\u5230\u9752\u7750\uff0c\u4e3b\u8981\u6709\u4ee5\u4e0b\u51e0\u4e2a\u539f\u56e0\uff1a<\/p>\n<h3>1. <strong>\u8d85\u5f3a\u78b1\u6027\uff0c\u6e29\u548c\u64cd\u4f5c<\/strong><\/h3>\n<p>\u56db\u7532\u57fa\u80cd\u7684pKa\u9ad8\u8fbe12.6\uff0c\u8bf4\u660e\u5b83\u5728\u6c34\u4e2d\u5c31\u80fd\u91ca\u653e\u51fa\u5927\u91cfOH\u207b\uff0c\u4fc3\u8fdb\u53bb\u8d28\u5b50\u5316\u53cd\u5e94\u3002\u4f46\u5728\u5b9e\u9645\u4f7f\u7528\u4e2d\uff0c\u5b83\u53c8\u4e0d\u50cf\u6c22\u6c27\u5316\u94a0\u90a3\u6837\u201c\u813e\u6c14\u66b4\u8e81\u201d\uff0c\u5bf9\u8bbe\u5907\u548c\u64cd\u4f5c\u8005\u90fd\u6bd4\u8f83\u53cb\u597d\u3002<\/p>\n<h3>2. <strong>\u826f\u597d\u7684\u4eb2\u6838\u6027<\/strong><\/h3>\n<p>\u7531\u4e8e\u80cd\u57fa\u7684\u5171\u8f6d\u7ed3\u6784\uff0c\u4f7f\u5f97\u5b83\u5177\u5907\u4e00\u5b9a\u7684\u4eb2\u6838\u80fd\u529b\uff0c\u5728\u67d0\u4e9b\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\u4e2d\u53ef\u4ee5\u4f5c\u4e3a\u8f85\u52a9\u8bd5\u5242\u6216\u50ac\u5316\u5242\u3002<\/p>\n<h3>3. <strong>\u4f18\u5f02\u7684\u6eb6\u89e3\u6027<\/strong><\/h3>\n<p>\u4e0d\u7ba1\u662f\u6c34\u8fd8\u662f\u6709\u673a\u6eb6\u5242\uff0cTMG\u90fd\u80fd\u5f88\u597d\u5730\u878d\u5165\u5176\u4e2d\uff0c\u8fd9\u4f7f\u5f97\u5b83\u5728\u591a\u76f8\u50ac\u5316\u4f53\u7cfb\u4e2d\u4e5f\u80fd\u6e38\u5203\u6709\u4f59\u3002<\/p>\n<h3>4. <strong>\u73af\u4fdd\u4e14\u6613\u56de\u6536<\/strong><\/h3>\n<p>\u4e0e\u4f20\u7edf\u91d1\u5c5e\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u56db\u7532\u57fa\u80cd\u4e0d\u542b\u91cd\u91d1\u5c5e\uff0c\u73af\u5883\u53cb\u597d\uff0c\u90e8\u5206\u53cd\u5e94\u540e\u8fd8\u53ef\u901a\u8fc7\u9178\u5316\u6790\u51fa\uff0c\u5b9e\u73b0\u56de\u6536\u518d\u5229\u7528\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u5b9e\u6218\u6f14\u7ec3\uff1a\u56db\u7532\u57fa\u80cd\u5728\u54ea\u4e9b\u53cd\u5e94\u4e2d\u5927\u663e\u8eab\u624b\uff1f<\/h2>\n<p>\u63a5\u4e0b\u6765\u6211\u4eec\u5c31\u6765\u770b\u770b\u8fd9\u4f4d\u201c\u50ac\u5316\u5242\u5c0f\u738b\u5b50\u201d\u662f\u5982\u4f55\u5728\u4e0d\u540c\u7c7b\u578b\u7684\u6709\u673a\u53cd\u5e94\u4e2d\u65bd\u5c55\u624d\u534e\u7684\u3002<\/p>\n<h3>1. <strong>\u916f\u5316\u53cd\u5e94\u4e2d\u7684\u201c\u9690\u5f62\u63a8\u624b\u201d<\/strong><\/h3>\n<p>\u916f\u7c7b\u5316\u5408\u7269\u662f\u6709\u673a\u5316\u5b66\u4e2d\u6781\u4e3a\u5e38\u89c1\u7684\u4e00\u7c7b\u7269\u8d28\uff0c\u5e7f\u6cdb\u7528\u4e8e\u9999\u6599\u3001\u836f\u7269\u548c\u6750\u6599\u9886\u57df\u3002\u4f20\u7edf\u7684\u916f\u5316\u53cd\u5e94\u901a\u5e38\u9700\u8981\u6d53\u786b\u9178\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u4f46\u8150\u8680\u6027\u5f3a\u3001\u526f\u4ea7\u7269\u591a\u3002\u800c\u4f7f\u7528TMG\u4f5c\u50ac\u5316\u5242\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u907f\u514d\u8fd9\u4e9b\u95ee\u9898\uff0c\u8fd8\u80fd\u63d0\u9ad8\u4ea7\u7387\u3002<\/p>\n<p><strong>\u53cd\u5e94\u793a\u4f8b\uff1a<\/strong><\/p>\n<p>RCOOH + R\u2019OH \u2192 RCOOR\u2019 + H\u2082O<br \/>\n\uff08\u9178 + \u9187 \u2192 \u916f + \u6c34\uff09<\/p>\n<p>\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0cTMG\u53ef\u4ee5\u901a\u8fc7\u8131\u9664\u53cd\u5e94\u751f\u6210\u7684\u6c34\u6765\u63a8\u52a8\u5e73\u8861\u5411\u53f3\u79fb\u52a8\uff0c\u4ece\u800c\u63d0\u5347\u8f6c\u5316\u7387\u3002<\/p>\n<h3>2. <strong>Michael\u52a0\u6210\u53cd\u5e94\u4e2d\u7684\u201c\u52a0\u901f\u5668\u201d<\/strong><\/h3>\n<p>Michael\u52a0\u6210\u662f\u6784\u5efa\u78b3-\u78b3\u952e\u7684\u91cd\u8981\u624b\u6bb5\u4e4b\u4e00\u3002\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0cTMG\u53ef\u4ee5\u901a\u8fc7\u53bb\u8d28\u5b50\u5316\u4f7f\u4eb2\u6838\u8bd5\u5242\u66f4\u5177\u6d3b\u6027\uff0c\u4ece\u800c\u52a0\u5feb\u53cd\u5e94\u901f\u7387\u3002<\/p>\n<p><strong>\u53cd\u5e94\u7279\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u53cd\u5e94\u6761\u4ef6\u6e29\u548c<\/li>\n<li>\u65e0\u9700\u8fc7\u6e21\u91d1\u5c5e\u53c2\u4e0e<\/li>\n<li>\u5bf9\u5b98\u80fd\u56e2\u8010\u53d7\u6027\u5f3a<\/li>\n<\/ul>\n<h3>3. <strong>Knoevenagel\u7f29\u5408\u53cd\u5e94\u4e2d\u7684\u201c\u50ac\u5316\u5242\u62c5\u5f53\u201d<\/strong><\/h3>\n<p>\u8fd9\u4e2a\u53cd\u5e94\u4e3b\u8981\u7528\u4e8e\u5408\u6210\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u7269\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u533b\u836f\u548c\u5929\u7136\u4ea7\u7269\u5408\u6210\u4e2d\u3002<\/p>\n<p><strong>\u53cd\u5e94\u901a\u5f0f\uff1a<\/strong><\/p>\n<p>\u919b\/\u916e + \u6d3b\u6027\u4e9a\u7532\u57fa\u5316\u5408\u7269 \u2192 \u03b1,\u03b2-\u4e0d\u9971\u548c\u5316\u5408\u7269 + H\u2082O<\/p>\n<p>TMG\u5728\u8fd9\u91cc\u7684\u4f5c\u7528\u4e3b\u8981\u662f\u4fc3\u8fdb\u6d3b\u6027\u4e9a\u7532\u57fa\u5316\u5408\u7269\u7684\u53bb\u8d28\u5b50\u5316\uff0c\u4ece\u800c\u5f15\u53d1\u4eb2\u6838\u8fdb\u653b\u3002<\/p>\n<h3>4. <strong>Claisen\u91cd\u6392\u4e2d\u7684\u201c\u7a33\u5b9a\u5668\u201d<\/strong><\/h3>\n<p>\u867d\u7136Claisen\u91cd\u6392\u672c\u8eab\u5c5e\u4e8e\u70ed\u529b\u5b66\u9a71\u52a8\u7684\u5468\u73af\u53cd\u5e94\uff0c\u4f46\u5728\u67d0\u4e9b\u60c5\u51b5\u4e0b\uff0c\u52a0\u5165TMG\u53ef\u4ee5\u964d\u4f4e\u53cd\u5e94\u6e29\u5ea6\uff0c\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\uff0c\u540c\u65f6\u63d0\u9ad8\u533a\u57df\u9009\u62e9\u6027\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/37.jpg\" alt=\"\"><\/p>\n<h3>4. <strong>Claisen\u91cd\u6392\u4e2d\u7684\u201c\u7a33\u5b9a\u5668\u201d<\/strong><\/h3>\n<p>\u867d\u7136Claisen\u91cd\u6392\u672c\u8eab\u5c5e\u4e8e\u70ed\u529b\u5b66\u9a71\u52a8\u7684\u5468\u73af\u53cd\u5e94\uff0c\u4f46\u5728\u67d0\u4e9b\u60c5\u51b5\u4e0b\uff0c\u52a0\u5165TMG\u53ef\u4ee5\u964d\u4f4e\u53cd\u5e94\u6e29\u5ea6\uff0c\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\uff0c\u540c\u65f6\u63d0\u9ad8\u533a\u57df\u9009\u62e9\u6027\u3002<\/p>\n<h3>5. <strong>\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\u7684\u201c\u8f85\u52a9\u5927\u5e08\u201d<\/strong><\/h3>\n<p>\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u63a8\u5e7f\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u5c1d\u8bd5\u5c06TMG\u4e0e\u5176\u4ed6\u624b\u6027\u914d\u4f53\u7ed3\u5408\uff0c\u7528\u4e8e\u6784\u5efa\u624b\u6027\u4e2d\u5fc3\u3002\u4f8b\u5982\uff0c\u5728\u67d0\u4e9b\u4e0d\u5bf9\u79f0\u7f9f\u919b\u53cd\u5e94\u4e2d\uff0cTMG\u4e0e\u812f\u6c28\u9178\u7c7b\u50ac\u5316\u5242\u534f\u540c\u4f5c\u7528\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u56db\u7532\u57fa\u80cd vs \u5176\u4ed6\u5e38\u7528\u78b1\uff1a\u8c01\u624d\u662f\u771f\u6b63\u7684\u738b\u8005\uff1f<\/h2>\n<p>\u4e3a\u4e86\u8ba9\u5927\u5bb6\u66f4\u6e05\u695a\u5730\u4e86\u89e3TMG\u7684\u4f18\u52bf\uff0c\u6211\u4eec\u6765\u505a\u4e2a\u5c0f\u5bf9\u6bd4\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u7279\u6027<\/th>\n<th>TMG<\/th>\n<th>\u4e09\u4e59\u80fa\uff08TEA\uff09<\/th>\n<th>\u5421\u5576<\/th>\n<th>\u6c22\u6c27\u5316\u94a0\uff08NaOH\uff09<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u78b1\u6027\u5f3a\u5f31<\/td>\n<td>\u5f3a<\/td>\n<td>\u4e2d\u7b49\u504f\u5f31<\/td>\n<td>\u5f31<\/td>\n<td>\u6781\u5f3a<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u4e00\u822c<\/td>\n<td>\u5dee<\/td>\n<td>\u6781\u4f73<\/td>\n<\/tr>\n<tr>\n<td>\u53cd\u5e94\u6d3b\u6027<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u8150\u8680\u6027<\/td>\n<td>\u4f4e<\/td>\n<td>\u4f4e<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u662f\u5426\u91d1\u5c5e<\/td>\n<td>\u5426<\/td>\n<td>\u5426<\/td>\n<td>\u5426<\/td>\n<td>\u662f<\/td>\n<\/tr>\n<tr>\n<td>\u662f\u5426\u53ef\u56de\u6536<\/td>\n<td>\u53ef\u90e8\u5206\u56de\u6536<\/td>\n<td>\u4e0d\u6613\u56de\u6536<\/td>\n<td>\u4e0d\u6613\u56de\u6536<\/td>\n<td>\u53ef\u56de\u6536<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u5883\u5f71\u54cd<\/td>\n<td>\u5c0f<\/td>\n<td>\u5c0f<\/td>\n<td>\u5c0f<\/td>\n<td>\u8f83\u5927<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u53ef\u4ee5\u770b\u5230\uff0cTMG\u5728\u591a\u4e2a\u65b9\u9762\u90fd\u8868\u73b0\u51fa\u4e86\u5747\u8861\u751a\u81f3\u4f18\u8d8a\u7684\u6027\u80fd\u3002\u5c24\u5176\u662f\u5728\u7eff\u8272\u5316\u5b66\u548c\u53ef\u6301\u7eed\u53d1\u5c55\u65e5\u76ca\u91cd\u8981\u7684\u4eca\u5929\uff0c\u5b83\u65e0\u7591\u662f\u4e00\u4e2a\u503c\u5f97\u5927\u529b\u63a8\u5e7f\u7684\u6709\u673a\u78b1\u50ac\u5316\u5242\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u5de5\u4e1a\u5e94\u7528\u4e0e\u524d\u666f\u5c55\u671b<\/h2>\n<p>\u9664\u4e86\u5b9e\u9a8c\u5ba4\u7814\u7a76\uff0c\u56db\u7532\u57fa\u80cd\u5728\u5de5\u4e1a\u4e0a\u7684\u5e94\u7528\u4e5f\u8d8a\u6765\u8d8a\u5e7f\u6cdb\u3002\u7279\u522b\u662f\u5728\u5236\u836f\u3001\u519c\u836f\u3001\u9ad8\u5206\u5b50\u6750\u6599\u7b49\u9886\u57df\uff0c\u5b83\u7684\u8eab\u5f71\u9891\u9891\u51fa\u73b0\u3002<\/p>\n<h3>\u5728\u5236\u836f\u9886\u57df\u7684\u5e94\u7528\uff1a<\/h3>\n<p>\u8bb8\u591a\u836f\u7269\u5206\u5b50\u7684\u5408\u6210\u4e2d\u90fd\u4f1a\u6d89\u53ca\u5230\u916f\u5316\u3001\u9170\u80fa\u5316\u7b49\u6b65\u9aa4\uff0c\u800cTMG\u7684\u9ad8\u6548\u50ac\u5316\u80fd\u529b\u6b63\u597d\u6d3e\u4e0a\u7528\u573a\u3002\u4f8b\u5982\uff0c\u5728\u6297\u6291\u90c1\u836f\u5e15\u7f57\u897f\u6c40\uff08Paroxetine\uff09\u7684\u5408\u6210\u8def\u7ebf\u4e2d\uff0c\u5c31\u6709\u4f7f\u7528TMG\u4f5c\u4e3a\u8131\u6c34\u5242\u548c\u78b1\u6027\u50ac\u5316\u5242\u7684\u6210\u529f\u6848\u4f8b\u3002<\/p>\n<h3>\u5728\u9ad8\u5206\u5b50\u6750\u6599\u4e2d\u7684\u5e94\u7528\uff1a<\/h3>\n<p>\u5728\u805a\u6c28\u916f\u3001\u73af\u6c27\u6811\u8102\u7b49\u6750\u6599\u7684\u5236\u5907\u4e2d\uff0cTMG\u53ef\u4ee5\u7528\u4f5c\u56fa\u5316\u4fc3\u8fdb\u5242\uff0c\u663e\u8457\u7f29\u77ed\u56fa\u5316\u65f6\u95f4\uff0c\u63d0\u9ad8\u4ea7\u54c1\u6027\u80fd\u3002<\/p>\n<h3>\u5728\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u6f5c\u529b\uff1a<\/h3>\n<p>\u968f\u7740\u5168\u7403\u5bf9\u73af\u5883\u4fdd\u62a4\u610f\u8bc6\u7684\u589e\u5f3a\uff0c\u5f00\u53d1\u4f4e\u6bd2\u3001\u53ef\u56de\u6536\u3001\u975e\u91d1\u5c5e\u7684\u50ac\u5316\u5242\u6210\u4e3a\u8d8b\u52bf\u3002\u800cTMG\u6b63\u662f\u7b26\u5408\u8fd9\u4e00\u8981\u6c42\u7684\u7406\u60f3\u5019\u9009\u8005\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u7ed3\u8bed\uff1a\u56db\u7532\u57fa\u80cd\uff0c\u4e0d\u53ea\u662f\u4e00\u4e2a\u78b1\u90a3\u4e48\u7b80\u5355<\/h2>\n<p>\u56de\u987e\u5168\u6587\uff0c\u6211\u4eec\u53ef\u4ee5\u770b\u5230\uff0c\u56db\u7532\u57fa\u80cd\u4e0d\u4ec5\u4ec5\u662f\u4e00\u4e2a\u666e\u901a\u7684\u6709\u673a\u78b1\uff0c\u5b83\u66f4\u50cf\u662f\u4e00\u4e2a\u5168\u80fd\u578b\u9009\u624b\uff0c\u5728\u5404\u7c7b\u6709\u673a\u53cd\u5e94\u4e2d\u90fd\u80fd\u627e\u5230\u81ea\u5df1\u7684\u4f4d\u7f6e\u3002\u5b83\u65e2\u4e0d\u50cf\u4f20\u7edf\u91d1\u5c5e\u50ac\u5316\u5242\u90a3\u6837\u201c\u6c89\u91cd\u201d\uff0c\u4e5f\u4e0d\u50cf\u4e00\u4e9b\u5f3a\u78b1\u90a3\u6837\u201c\u7c97\u66b4\u201d\uff0c\u800c\u662f\u4ee5\u4e00\u79cd\u6e29\u548c\u800c\u9ad8\u6548\u7684\u65b9\u5f0f\uff0c\u9ed8\u9ed8\u5730\u63a8\u52a8\u7740\u5316\u5b66\u53cd\u5e94\u5411\u524d\u8fc8\u8fdb\u3002<\/p>\n<p>\u5728\u672a\u6765\uff0c\u968f\u7740\u4eba\u4eec\u5bf9\u7eff\u8272\u5316\u5b66\u548c\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u91cd\u89c6\u4e0d\u65ad\u63d0\u9ad8\uff0c\u76f8\u4fe1\u56db\u7532\u57fa\u80cd\u7684\u5e94\u7528\u8303\u56f4\u4f1a\u8d8a\u6765\u8d8a\u5e7f\uff0c\u5b83\u7684\u4ef7\u503c\u4e5f\u4f1a\u88ab\u66f4\u591a\u4eba\u6240\u8ba4\u8bc6\u548c\u6b23\u8d4f\u3002<\/p>\n<hr \/>\n<h2>\u53c2\u8003\u6587\u732e\uff08\u56fd\u5185\u5916\u7ecf\u5178\u8bba\u6587\u63a8\u8350\uff09<\/h2>\n<p>\u4ee5\u4e0b\u662f\u4e00\u4e9b\u5173\u4e8e\u56db\u7532\u57fa\u80cd\u5728\u6709\u673a\u5408\u6210\u4e2d\u5e94\u7528\u7684\u7ecf\u5178\u6587\u732e\uff0c\u4f9b\u6709\u5174\u8da3\u8fdb\u4e00\u6b65\u6df1\u5165\u7814\u7a76\u7684\u670b\u53cb\u53c2\u8003\uff1a<\/p>\n<ol>\n<li>\n<p><strong>Corey, E. J., &amp; Cheng, X.-M. (1989).<\/strong> <em>The Logic of Chemical Synthesis<\/em>. Wiley.<br \/>\n\uff08\u672c\u4e66\u867d\u672a\u76f4\u63a5\u8ba8\u8bbaTMG\uff0c\u4f46\u5bf9\u6709\u673a\u50ac\u5316\u5242\u7684\u903b\u8f91\u5206\u6790\u6781\u5177\u542f\u53d1\u610f\u4e49\uff09\n<\/li>\n<li>\n<p><strong>Sharghi, H., &amp; Eskandari, M. M. (2006).<\/strong> \u201cTetramethylguanidine as an efficient catalyst for the synthesis of quinazolinones.\u201d <em>Journal of Molecular Catalysis A: Chemical<\/em>, 254(1-2), 146\u2013151.\n<\/li>\n<li>\n<p><strong>Zhou, Y., et al. (2012).<\/strong> \u201cTMG-catalyzed one-pot synthesis of 2-amino-4H-chromenes in aqueous media.\u201d <em>Green Chemistry<\/em>, 14(5), 1345\u20131350.\n<\/li>\n<li>\n<p><strong>\u674e\u6653\u4e1c, \u738b\u5fd7\u5f3a. (2015).<\/strong> \u201c\u56db\u7532\u57fa\u80cd\u50ac\u5316\u916f\u5316\u53cd\u5e94\u7684\u7814\u7a76\u8fdb\u5c55.\u201d\u300a\u7cbe\u7ec6\u5316\u5de5\u300b, 32(6), 587\u2013592.\n<\/li>\n<li>\n<p><strong>Liu, R., et al. (2018).<\/strong> \u201cAsymmetric Michael addition catalyzed by TMG-based bifunctional organocatalysts.\u201d <em>Organic &amp; Biomolecular Chemistry<\/em>, 16(22), 4035\u20134043.\n<\/li>\n<li>\n<p><strong>\u5f20\u4f1f, \u9648\u78ca. (2020).<\/strong> \u201c\u7eff\u8272\u50ac\u5316\u5242\u56db\u7532\u57fa\u80cd\u5728\u836f\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528.\u201d\u300a\u5316\u5b66\u901a\u62a5\u300b, 83(11), 1012\u20131018.\n<\/li>\n<li>\n<p><strong>Baskaran, S., et al. (2004).<\/strong> \u201cTetramethylguanidine (TMG): A versatile base and catalyst in organic synthesis.\u201d <em>Synthesis<\/em>, 2004(08), 1169\u20131182.\n<\/li>\n<\/ol>\n<p>\u8fd9\u4e9b\u6587\u732e\u6db5\u76d6\u4e86\u56db\u7532\u57fa\u80cd\u5728\u4e0d\u540c\u53cd\u5e94\u7c7b\u578b\u3001\u4e0d\u540c\u5e94\u7528\u573a\u666f\u4e0b\u7684\u7814\u7a76\u6210\u679c\uff0c\u65e2\u6709\u7406\u8bba\u63a2\u8ba8\u4e5f\u6709\u5b9e\u9a8c\u9a8c\u8bc1\uff0c\u662f\u6df1\u5165\u4e86\u89e3\u8be5\u50ac\u5316\u5242\u4e0d\u53ef\u591a\u5f97\u7684\u8d44\u6599\u3002<\/p>\n<hr \/>\n<p>\u5982\u679c\u4f60\u6b63\u5728\u5bfb\u627e\u4e00\u4e2a\u65e2\u9ad8\u6548\u53c8\u73af\u4fdd\u3001\u65e2\u5b9e\u7528\u53c8\u6709\u8da3\u7684\u6709\u673a\u78b1\u50ac\u5316\u5242\uff0c\u4e0d\u59a8\u8bd5\u8bd5\u56db\u7532\u57fa\u80cd\u3002\u4e5f\u8bb8\u5b83\u5c31\u662f\u4f60\u4e0b\u4e00\u6b21\u6210\u529f\u53cd\u5e94\u7684\u5173\u952e\u6240\u5728\uff01<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n<ul>\n<li>\n<h3>NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-14 \u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5bc6\u5c01\u80f6\u548c\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-15 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6bd4A-14\u6d3b\u6027\u4f4e\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-16 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\u548c\u4e00\u5b9a\u7684\u8010\u6c34\u89e3\u6027\uff0c\u7ec4\u5408\u6599\u50a8\u5b58\u65f6\u95f4\u957f\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-128 \u9002\u7528\u4e8e\u805a\u6c28\u916f\u53cc\u7ec4\u4efd\u5feb\u901f\u56fa\u5316\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5728\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u50ac\u5316\u6d3b\u6027\u5f3a\uff0c\u7279\u522b\u9002\u5408\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-129 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u5ef6\u8fdf\u6548\u679c\uff0c\u4e0e\u6c34\u7684\u7a33\u5b9a\u6027\u8f83\u5f3a\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-138 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u826f\u597d\u7684\u6d41\u52a8\u6027\u548c\u8010\u6c34\u89e3\u6027\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-154 \u9002\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-159 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u53ef\u7528\u6765\u66ff\u4ee3A-14\uff0c\u6dfb\u52a0\u91cf\u4e3aA-14\u768450-60%\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT MB20 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u66ff\u4ee3\u8f6f\u8d28\u5757\u72b6\u6ce1\u6cab\u3001\u9ad8\u5bc6\u5ea6\u8f6f\u8d28\u6ce1\u6cab\u3001\u55b7\u6d82\u6ce1\u6cab\u3001\u5fae\u5b54\u6ce1\u6cab\u4ee5\u53ca\u786c\u8d28\u6ce1\u6cab\u4f53\u7cfb\u4e2d\u7684\u9521\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6d3b\u6027\u6bd4\u6709\u673a\u9521\u76f8\u5bf9\u8f83\u4f4e\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT T-12 \u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff0c\u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u9002\u7528\u4e8e\u805a\u919a\u578b\u9ad8\u5bc6\u5ea6\u7ed3\u6784\u6ce1\u6cab\uff0c\u8fd8\u7528\u4e8e\u805a\u6c28\u916f\u6d82\u6599\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5ba4\u6e29\u56fa\u5316\u7845\u6a61\u80f6\u7b49\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT T-125 \u6709\u673a\u9521\u7c7b\u5f3a\u51dd\u80f6\u50ac\u5316\u5242\uff0c\u4e0e\u5176\u4ed6\u7684\u4e8c\u4e01\u57fa\u9521\u50ac\u5316\u5242\u76f8\u6bd4\uff0cT-125\u50ac\u5316\u5242\u5bf9\u6c28\u57fa\u7532\u9178\u916f\u53cd\u5e94\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u800c\u4e14\u6539\u5584\u4e86\u6c34\u89e3\u7a33\u5b9a\u6027\uff0c\u9002\u7528\u4e8e\u786c\u8d28\u805a\u6c28\u916f\u55b7\u6d82\u6ce1\u6cab\u3001\u6a21\u5851\u6ce1\u6cab\u53caCASE\u5e94\u7528\u4e2d\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>\u56db\u7532\u57fa\u80cd\uff1a\u6709\u673a\u5408\u6210\u4e2d\u7684\u201c\u50ac\u5316\u5242\u5c0f\u738b\u5b50\u201d \u5728\u6709\u673a\u5408\u6210\u8fd9\u4e2a\u4e94\u5f69\u6591\u6593\u7684\u5316\u5b66\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u662f\u4e00\u7fa4\u9ed8\u9ed8\u65e0\u95fb\u5374\u4e0d\u53ef\u6216\u7f3a\u7684\u201c\u5e55\u540e\u82f1\u96c4\u201d\u3002\u5b83\u4eec\u4e0d\u55a7\u54d7\u3001\u4e0d\u5f20\u626c\uff0c\u5374\u603b\u80fd\u5728\u5173\u952e\u65f6\u523b\u633a\u8eab\u800c\u51fa\uff0c\u8ba9\u53cd\u5e94\u4e8b\u534a\u529f\u500d\u3002\u800c\u5728\u8fd9\u4e9b\u50ac\u5316\u5242\u4e2d\uff0c\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine\uff0c\u7b80\u79f0TMG\uff09\u53ef\u4ee5\u8bf4\u662f\u4e00\u4f4d\u4f4e\u8c03\u5374\u9ad8\u6548\u7684\u201c\u5b9e\u529b\u6d3e\u9009\u624b\u201d\uff0c\u5b83\u4e0d\u4ec5\u5728\u4f17 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.zuheliao.com\/index.php\/wp-json\/wp\/v2\/posts\/10539"}],"collection":[{"href":"https:\/\/www.zuheliao.com\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.zuheliao.com\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.zuheliao.com\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.zuheliao.com\/index.php\/wp-json\/wp\/v2\/comments?post=10539"}],"version-history":[{"count":0,"href":"https:\/\/www.zuheliao.com\/index.php\/wp-json\/wp\/v2\/posts\/10539\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.zuheliao.com\/index.php\/wp-json\/wp\/v2\/media?parent=10539"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.zuheliao.com\/index.php\/wp-json\/wp\/v2\/categories?post=10539"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.zuheliao.com\/index.php\/wp-json\/wp\/v2\/tags?post=10539"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}