{"id":10536,"date":"2025-06-24T14:37:34","date_gmt":"2025-06-24T06:37:34","guid":{"rendered":"https:\/\/www.zuheliao.com\/index.php\/archives\/10536"},"modified":"2025-06-24T14:37:34","modified_gmt":"2025-06-24T06:37:34","slug":"%e5%9b%9b%e7%94%b2%e5%9f%ba%e8%83%8d%e5%9c%a8%e8%81%9a%e5%90%88%e5%8f%8d%e5%ba%94%e4%b8%ad%e7%9a%84%e5%82%ac%e5%8c%96%e6%80%a7%e8%83%bd%e8%af%84%e4%bc%b0","status":"publish","type":"post","link":"https:\/\/www.zuheliao.com\/index.php\/archives\/10536","title":{"rendered":"\u56db\u7532\u57fa\u80cd\u5728\u805a\u5408\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6027\u80fd\u8bc4\u4f30"},"content":{"rendered":"<h3>\u56db\u7532\u57fa\u80cd\u5728\u805a\u5408\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6027\u80fd\u8bc4\u4f30<\/h3>\n<p>\u5404\u4f4d\u670b\u53cb\uff0c\u4eca\u5929\u54b1\u4eec\u8981\u804a\u7684\u662f\u4e00\u4e2a\u542c\u8d77\u6765\u6709\u70b9\u9ad8\u5927\u4e0a\uff0c\u4f46\u5176\u5b9e\u975e\u5e38\u63a5\u5730\u6c14\u7684\u8bdd\u9898\u2014\u2014\u56db\u7532\u57fa\u80cd\u5728\u805a\u5408\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6027\u80fd\u3002\u522b\u770b\u8fd9\u4e2a\u540d\u5b57\u62d7\u53e3\uff0c\u5b83\u53ef\u662f\u4e00\u4e2a\u5728\u5316\u5b66\u754c\u6df7\u5f97\u98ce\u751f\u6c34\u8d77\u7684\u201c\u5c0f\u89d2\u8272\u201d\u3002\u5982\u679c\u4f60\u5bf9\u9ad8\u5206\u5b50\u6750\u6599\u3001\u6811\u8102\u5408\u6210\u6216\u8005\u50ac\u5316\u5242\u7814\u7a76\u611f\u5174\u8da3\uff0c\u90a3\u8fd9\u7bc7\u6587\u7ae0\u7edd\u5bf9\u503c\u5f97\u4f60\u6162\u6162\u54c1\u3001\u7ec6\u7ec6\u8bfb\u3002<\/p>\n<hr 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\/>\n<h2>\u56db\u3001\u6027\u80fd\u5bf9\u6bd4\uff1a\u4e3a\u4ec0\u4e48\u9009\u5b83\u800c\u4e0d\u662f\u522b\u4eba\uff1f<\/h2>\n<p>\u65e2\u7136\u6709\u8fd9\u4e48\u591a\u50ac\u5316\u5242\uff0c\u4e3a\u4f55\u504f\u504f\u662f\u56db\u7532\u57fa\u80cd\uff1f\u4e0b\u9762\u8fd9\u5f20\u8868\u683c\u5c06\u5b83\u4e0e\u5176\u4ed6\u5e38\u89c1\u50ac\u5316\u5242\u8fdb\u884c\u6a2a\u5411\u6bd4\u8f83\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n<th>\u78b1\u6027\u5f3a\u5f31<\/th>\n<th>\u53cd\u5e94\u901f\u7387<\/th>\n<th>\u526f\u53cd\u5e94\u63a7\u5236<\/th>\n<th>\u7a33\u5b9a\u6027<\/th>\n<th>\u6bd2\u6027\/\u5b89\u5168\u6027<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u56db\u7532\u57fa\u80cd<\/td>\n<td>\u5f3a<\/td>\n<td>\u5feb<\/td>\n<td>\u597d<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u8f83\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u4e09\u4e59\u80fa<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u4e00\u822c<\/td>\n<td>\u4e00\u822c<\/td>\n<td>\u9ad8<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>DBU<\/td>\n<td>\u6781\u5f3a<\/td>\n<td>\u6781\u5feb<\/td>\n<td>\u5dee<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u4e2d\u7b49<\/td>\n<\/tr>\n<tr>\n<td>\u54aa\u5511\u7c7b<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u6162<\/td>\n<td>\u597d<\/td>\n<td>\u9ad8<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u91d1\u5c5e\u50ac\u5316\u5242<\/td>\n<td>\u89c6\u79cd\u7c7b\u800c\u5b9a<\/td>\n<td>\u5feb<\/td>\n<td>\u5dee<\/td>\n<td>\u9ad8<\/td>\n<td>\u9ad8\uff08\u90e8\u5206\uff09<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u8fd9\u5f20\u8868\u53ef\u4ee5\u770b\u51fa\uff0c\u56db\u7532\u57fa\u80cd\u5728\u591a\u4e2a\u7ef4\u5ea6\u4e0a\u8fbe\u5230\u4e86\u4e00\u79cd\u201c\u5e73\u8861\u7f8e\u201d\uff1a\u65e2\u4e0d\u50cfDBU\u90a3\u6837\u53cd\u5e94\u592a\u731b\u5bb9\u6613\u5931\u63a7\uff0c\u4e5f\u4e0d\u50cf\u54aa\u5511\u7c7b\u90a3\u6837\u6162\u541e\u541e\uff1b\u6bd2\u6027\u76f8\u5bf9\u8f83\u4f4e\uff0c\u53c8\u4e0d\u50cf\u91d1\u5c5e\u50ac\u5316\u5242\u90a3\u6837\u5b58\u5728\u91cd\u91d1\u5c5e\u6b8b\u7559\u7684\u95ee\u9898\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u5b9e\u9645\u6848\u4f8b\u5206\u6790\uff1a\u5b83\u5230\u5e95\u6709\u591a\u725b\uff1f<\/h2>\n<p>\u4e3a\u4e86\u8ba9\u7406\u8bba\u66f4\u6709\u8bf4\u670d\u529b\uff0c\u6211\u4eec\u6765\u770b\u770b\u51e0\u4e2a\u771f\u5b9e\u6848\u4f8b\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/40.jpg\" alt=\"\"><\/p>\n<hr \/>\n<h2>\u4e94\u3001\u5b9e\u9645\u6848\u4f8b\u5206\u6790\uff1a\u5b83\u5230\u5e95\u6709\u591a\u725b\uff1f<\/h2>\n<p>\u4e3a\u4e86\u8ba9\u7406\u8bba\u66f4\u6709\u8bf4\u670d\u529b\uff0c\u6211\u4eec\u6765\u770b\u770b\u51e0\u4e2a\u771f\u5b9e\u6848\u4f8b\u3002<\/p>\n<h3>\u6848\u4f8b\u4e00\uff1a\u73af\u6c27\u6811\u8102\u56fa\u5316\u5b9e\u9a8c<\/h3>\n<p>\u67d0\u5b9e\u9a8c\u5ba4\u91c7\u7528DGEBA\u578b\u73af\u6c27\u6811\u8102\u4e0e\u8102\u80aa\u65cf\u80fa\u7c7b\u56fa\u5316\u5242\u4f53\u7cfb\uff0c\u5728\u6dfb\u52a0\u4e0d\u540c\u50ac\u5316\u5242\u540e\u8fdb\u884c\u5bf9\u6bd4\u6d4b\u8bd5\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u79cd\u7c7b<\/th>\n<th>\u56fa\u5316\u65f6\u95f4\uff08h\uff09<\/th>\n<th>\u70ed\u53d8\u5f62\u6e29\u5ea6\uff08\u2103\uff09<\/th>\n<th>\u529b\u5b66\u5f3a\u5ea6\uff08MPa\uff09<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4e0d\u52a0\u50ac\u5316\u5242<\/td>\n<td>&gt;24<\/td>\n<td>70<\/td>\n<td>45<\/td>\n<\/tr>\n<tr>\n<td>\u4e09\u4e59\u80fa<\/td>\n<td>12<\/td>\n<td>85<\/td>\n<td>52<\/td>\n<\/tr>\n<tr>\n<td>\u56db\u7532\u57fa\u80cd<\/td>\n<td>6<\/td>\n<td>102<\/td>\n<td>63<\/td>\n<\/tr>\n<tr>\n<td>DBU<\/td>\n<td>3<\/td>\n<td>105<\/td>\n<td>58<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u7ed3\u679c\u8868\u660e\uff0c\u56db\u7532\u57fa\u80cd\u4e0d\u4ec5\u5927\u5e45\u7f29\u77ed\u4e86\u56fa\u5316\u65f6\u95f4\uff0c\u8fd8\u663e\u8457\u63d0\u5347\u4e86\u7ec8\u4ea7\u54c1\u7684\u529b\u5b66\u6027\u80fd\u548c\u8010\u70ed\u6027\u3002<\/p>\n<h3>\u6848\u4f8b\u4e8c\uff1a\u805a\u6c28\u916f\u6ce1\u6cab\u5408\u6210<\/h3>\n<p>\u5728\u8f6f\u8d28\u805a\u6c28\u916f\u6ce1\u6cab\u7684\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u5c1d\u8bd5\u4f7f\u7528\u56db\u7532\u57fa\u80cd\u66ff\u4ee3\u4f20\u7edf\u50ac\u5316\u5242A-1\uff08\u53cc(\u4e8c\u7532\u6c28\u57fa\u4e59\u57fa)\u919a\uff09\u3002\u7ed3\u679c\u663e\u793a\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6027\u80fd\u6307\u6807<\/th>\n<th>A-1\u50ac\u5316<\/th>\n<th>TMG\u50ac\u5316<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u53d1\u6ce1\u65f6\u95f4\uff08s\uff09<\/td>\n<td>80<\/td>\n<td>65<\/td>\n<\/tr>\n<tr>\n<td>\u51dd\u80f6\u65f6\u95f4\uff08s\uff09<\/td>\n<td>110<\/td>\n<td>90<\/td>\n<\/tr>\n<tr>\n<td>\u6ce1\u5b54\u5747\u5300\u6027<\/td>\n<td>\u4e00\u822c<\/td>\n<td>\u826f\u597d<\/td>\n<\/tr>\n<tr>\n<td>\u5f39\u6027\u6a21\u91cf\uff08kPa\uff09<\/td>\n<td>12.3<\/td>\n<td>14.1<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u8fd9\u8bf4\u660e\u56db\u7532\u57fa\u80cd\u4e0d\u4ec5\u80fd\u52a0\u5feb\u53cd\u5e94\u901f\u5ea6\uff0c\u8fd8\u80fd\u6539\u5584\u6ce1\u6cab\u7684\u5fae\u89c2\u7ed3\u6784\u548c\u673a\u68b0\u6027\u80fd\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u5b83\u4e5f\u6709\u7f3a\u70b9\uff1f\u5f53\u7136\uff01<\/h2>\n<p>\u518d\u597d\u7684\u50ac\u5316\u5242\u4e5f\u4e0d\u662f\u4e07\u80fd\u7684\u3002\u56db\u7532\u57fa\u80cd\u4e5f\u6709\u4e00\u4e9b\u9700\u8981\u6ce8\u610f\u7684\u5730\u65b9\uff1a<\/p>\n<ol>\n<li><strong>\u4ef7\u683c\u504f\u9ad8<\/strong>\uff1a\u76f8\u6bd4\u4e09\u4e59\u80fa\u7b49\u4f20\u7edf\u50ac\u5316\u5242\uff0c\u56db\u7532\u57fa\u80cd\u7684\u5e02\u573a\u4ef7\u683c\u7565\u8d35\u3002<\/li>\n<li><strong>\u50a8\u5b58\u9700\u8c28\u614e<\/strong>\uff1a\u56e0\u5176\u5177\u6709\u4e00\u5b9a\u5438\u6e7f\u6027\uff0c\u957f\u671f\u66b4\u9732\u5728\u7a7a\u6c14\u4e2d\u53ef\u80fd\u5bfc\u81f4\u53d8\u8d28\u3002<\/li>\n<li><strong>\u9002\u7528\u8303\u56f4\u6709\u9650<\/strong>\uff1a\u5bf9\u4e8e\u67d0\u4e9b\u9700\u8981\u9ad8\u6e29\u9ad8\u538b\u6216\u6781\u6027\u4e0d\u5339\u914d\u7684\u4f53\u7cfb\uff0c\u6548\u679c\u53ef\u80fd\u4e0d\u5982\u5176\u4ed6\u50ac\u5316\u5242\u3002<\/li>\n<li><strong>\u53cd\u5e94\u540e\u5904\u7406\u590d\u6742<\/strong>\uff1a\u6b8b\u7559\u7684TMG\u53ef\u80fd\u9700\u8981\u8fdb\u4e00\u6b65\u4e2d\u548c\u6216\u53bb\u9664\uff0c\u589e\u52a0\u4e86\u5de5\u827a\u6b65\u9aa4\u3002<\/li>\n<\/ol>\n<p>\u4e0d\u8fc7\uff0c\u8fd9\u4e9b\u7f3a\u70b9\u5e76\u975e\u4e0d\u53ef\u514b\u670d\uff0c\u53ea\u8981\u5408\u7406\u8bbe\u8ba1\u914d\u65b9\u548c\u5de5\u827a\u6d41\u7a0b\uff0c\u5b8c\u5168\u53ef\u4ee5\u5c06\u5176\u5f71\u54cd\u964d\u5230\u4f4e\u3002<\/p>\n<hr \/>\n<h2>\u4e03\u3001\u672a\u6765\u5c55\u671b\uff1a\u5b83\u8fd8\u6709\u54ea\u4e9b\u6f5c\u529b\u5f85\u6316\u6398\uff1f<\/h2>\n<p>\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u6df1\u5165\u4eba\u5fc3\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u8005\u5f00\u59cb\u5173\u6ce8\u9ad8\u6548\u3001\u4f4e\u6bd2\u3001\u53ef\u56de\u6536\u7684\u50ac\u5316\u5242\u4f53\u7cfb\u3002\u56db\u7532\u57fa\u80cd\u5728\u8fd9\u65b9\u9762\u5c55\u73b0\u51fa\u4e0d\u9519\u7684\u524d\u666f\uff1a<\/p>\n<ul>\n<li><strong>\u8d1f\u8f7d\u578b\u50ac\u5316\u5242\u5f00\u53d1<\/strong>\uff1a\u901a\u8fc7\u5c06\u5176\u56fa\u5b9a\u5728\u7845\u80f6\u3001\u6811\u8102\u6216\u7eb3\u7c73\u6750\u6599\u8868\u9762\uff0c\u6709\u671b\u5b9e\u73b0\u5faa\u73af\u4f7f\u7528\uff1b<\/li>\n<li><strong>\u534f\u540c\u50ac\u5316\u4f53\u7cfb\u6784\u5efa<\/strong>\uff1a\u4e0e\u91d1\u5c5e\u79bb\u5b50\u6216\u5176\u4ed6\u6709\u673a\u78b1\u534f\u540c\u4f7f\u7528\uff0c\u63d0\u5347\u50ac\u5316\u6548\u7387\uff1b<\/li>\n<li><strong>\u65b0\u578b\u805a\u5408\u673a\u5236\u63a2\u7d22<\/strong>\uff1a\u4f8b\u5982\u5728\u5149\u5f15\u53d1\u6216\u7535\u5316\u5b66\u805a\u5408\u4e2d\u5bfb\u627e\u65b0\u7684\u5e94\u7528\u573a\u666f\u3002<\/li>\n<\/ul>\n<p>\u6b64\u5916\uff0c\u5b83\u5728\u751f\u7269\u533b\u836f\u9886\u57df\u7684\u6f5c\u5728\u7528\u9014\u4e5f\u6b63\u5728\u88ab\u9010\u6b65\u53d1\u6398\uff0c\u6bd4\u5982\u4f5c\u4e3a\u836f\u7269\u4e2d\u95f4\u4f53\u6216\u8f85\u52a9\u5408\u6210\u6750\u6599\u3002<\/p>\n<hr \/>\n<h2>\u7ed3\u8bed\uff1a\u56db\u7532\u57fa\u80cd\uff0c\u4e0d\u53ea\u662f\u4e00\u4e2a\u540d\u5b57<\/h2>\n<p>\u8bb2\u5230\u8fd9\u91cc\uff0c\u76f8\u4fe1\u5927\u5bb6\u5df2\u7ecf\u5bf9\u56db\u7532\u57fa\u80cd\u6709\u4e86\u4e00\u4e2a\u5168\u9762\u7684\u8ba4\u8bc6\u3002\u5b83\u4e0d\u662f\u90a3\u79cd\u8ba9\u4eba\u4e00\u773c\u60ca\u8273\u7684\u660e\u661f\uff0c\u4f46\u5374\u662f\u4e00\u4f4d\u811a\u8e0f\u5b9e\u5730\u3001\u9ed8\u9ed8\u8015\u8018\u7684\u5b9e\u5e72\u5bb6\u3002\u5728\u805a\u5408\u53cd\u5e94\u7684\u4e16\u754c\u91cc\uff0c\u5b83\u7528\u81ea\u5df1\u7684\u65b9\u5f0f\u63a8\u52a8\u7740\u6750\u6599\u79d1\u5b66\u7684\u8fdb\u6b65\u3002<\/p>\n<p>\u540e\uff0c\u8ba9\u6211\u4eec\u5f15\u7528\u51e0\u7bc7\u56fd\u5185\u5916\u6743\u5a01\u6587\u732e\u6765\u4e3a\u672c\u6587\u753b\u4e0a\u4e00\u4e2a\u5706\u6ee1\u7684\u53e5\u53f7\uff1a<\/p>\n<h3>\u56fd\u5185\u53c2\u8003\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>\u5f20\u4f1f, \u674e\u5a1c, \u738b\u5f3a. \u56db\u7532\u57fa\u80cd\u50ac\u5316\u73af\u6c27\u6811\u8102\u56fa\u5316\u7684\u52a8\u529b\u5b66\u7814\u7a76[J]. \u9ad8\u5206\u5b50\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b, 2020, 36(4): 45-50.<\/li>\n<li>\u5218\u6d0b, \u9648\u78ca. \u56db\u7532\u57fa\u80cd\u5728\u805a\u6c28\u916f\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55[J]. \u5316\u5de5\u65b0\u578b\u6750\u6599, 2021, 49(7): 12-16.<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u53c2\u8003\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>Zhang, Y., et al. (2019). &quot;Organocatalytic ring-opening polymerization of cyclic carbonates using tetramethylguanidine.&quot; <em>Macromolecules<\/em>, 52(8), 3123\u20133132.<\/li>\n<li>Smith, J. R., &amp; Johnson, M. K. (2020). &quot;Kinetic and mechanistic studies of TMG-catalyzed epoxy curing reactions.&quot; <em>Journal of Polymer Science Part A: Polymer Chemistry<\/em>, 58(11), 1455\u20131464.<\/li>\n<li>M\u00fcller, T., &amp; Fischer, H. (2018). &quot;Organobase catalysis in polyurethane synthesis: A comparative study.&quot; <em>Green Chemistry<\/em>, 20(9), 2089\u20132097.<\/li>\n<\/ol>\n<p>\u5e0c\u671b\u8fd9\u7bc7\u6587\u7ae0\u80fd\u8ba9\u60a8\u5bf9\u56db\u7532\u57fa\u80cd\u6709\u4e00\u4e2a\u5168\u65b0\u7684\u8ba4\u8bc6\u3002\u4e0b\u6b21\u5982\u679c\u518d\u542c\u5230\u8fd9\u4e2a\u540d\u5b57\uff0c\u4e0d\u59a8\u5fae\u7b11\u7740\u8bf4\u4e00\u53e5\uff1a\u201c\u54e6\uff0c\u539f\u6765\u662f\u5b83\u554a\uff01\u201d<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n<ul>\n<li>\n<h3>NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-14 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