{"id":10532,"date":"2025-06-24T14:32:16","date_gmt":"2025-06-24T06:32:16","guid":{"rendered":"https:\/\/www.zuheliao.com\/index.php\/archives\/10532"},"modified":"2025-06-24T14:32:16","modified_gmt":"2025-06-24T06:32:16","slug":"%e5%88%86%e6%9e%90%e5%9b%9b%e7%94%b2%e5%9f%ba%e8%83%8d%e5%af%b9%e5%8f%8d%e5%ba%94%e9%80%9f%e5%ba%a6%e5%92%8c%e4%ba%a7%e7%89%a9%e9%80%89%e6%8b%a9%e6%80%a7%e7%9a%84%e5%bd%b1%e5%93%8d","status":"publish","type":"post","link":"https:\/\/www.zuheliao.com\/index.php\/archives\/10532","title":{"rendered":"\u5206\u6790\u56db\u7532\u57fa\u80cd\u5bf9\u53cd\u5e94\u901f\u5ea6\u548c\u4ea7\u7269\u9009\u62e9\u6027\u7684\u5f71\u54cd"},"content":{"rendered":"<p><strong>\u56db\u7532\u57fa\u80cd\u5bf9\u53cd\u5e94\u901f\u5ea6\u548c\u4ea7\u7269\u9009\u62e9\u6027\u7684\u5f71\u54cd\u5206\u6790<\/strong><\/p>\n<p>\u5728\u5316\u5b66\u53cd\u5e94\u7684\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u662f\u4e00\u4f4d\u7ecf\u9a8c\u4e30\u5bcc\u7684\u6307\u6325\u5bb6\uff0c\u5b83\u4e0d\u4eb2\u81ea\u4e0a\u9635\u6f14\u594f\uff0c\u5374\u80fd\u5de6\u53f3\u6574\u4e2a\u4ea4\u54cd\u4e50\u7684\u8282\u594f\u4e0e\u548c\u8c10\u3002\u800c\u5728\u8fd9\u4f17\u591a\u201c\u6307\u6325\u5bb6\u201d\u4e2d\uff0c\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine\uff0c\u7b80\u79f0TMG\uff09\u56e0\u5176\u72ec\u7279\u7684\u78b1\u6027\u548c\u7ed3\u6784\u7279\u6027\uff0c\u5728\u6709\u673a\u5408\u6210\u9886\u57df\u9010\u6e10\u5d2d\u9732\u5934\u89d2\uff0c\u6210\u4e3a\u4e00\u79cd\u4e0d\u53ef\u5ffd\u89c6\u7684\u53cd\u5e94\u8c03\u63a7\u56e0\u5b50\u3002<\/p>\n<p>\u672c\u6587\u5c06\u56f4\u7ed5\u56db\u7532\u57fa\u80cd\u8fd9\u4e00\u5316\u5408\u7269\u5c55\u5f00\uff0c\u6df1\u5165\u63a2\u8ba8\u5176\u5728\u4e0d\u540c\u53cd\u5e94\u4f53\u7cfb\u4e2d\u5bf9\u53cd\u5e94\u901f\u7387\u53ca\u4ea7\u7269\u9009\u62e9\u6027\u7684\u5f71\u54cd\u673a\u5236\uff0c\u5e76\u7ed3\u5408\u5b9e\u9a8c\u6570\u636e\u3001\u4ea7\u54c1\u53c2\u6570\u4ee5\u53ca\u56fd\u5185\u5916\u7814\u7a76\u6210\u679c\uff0c\u5e26\u5927\u5bb6\u8d70\u8fdb\u8fd9\u4f4d\u201c\u4f4e\u8c03\u4f46\u9ad8\u6548\u201d\u7684\u5316\u5b66\u52a9\u624b\u7684\u4e16\u754c\u3002<\/p>\n<hr \/>\n<h2>\u4e00\u3001\u521d\u8bc6\u56db\u7532\u57fa\u80cd\uff1a\u4ece\u7ed3\u6784\u5230\u6027\u8d28<\/h2>\n<p>\u56db\u7532\u57fa\u80cd\uff0c\u5316\u5b66\u5f0f\u4e3aC\u2085H\u2081\u2083N\u2083\uff0c\u662f\u4e00\u79cd\u6709\u673a\u5f3a\u78b1\uff0c\u5916\u89c2\u4e3a\u767d\u8272\u6676\u4f53\u6216\u7c89\u672b\u72b6\u7269\u8d28\uff0c\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u6eb6\u89e3\u6027\u3002\u5176\u5206\u5b50\u7ed3\u6784\u4e2d\u5305\u542b\u4e00\u4e2a\u4e2d\u5fc3\u7684\u80cd\u57fa\u56e2\uff0c\u56db\u4e2a\u6c2e\u539f\u5b50\u88ab\u7532\u57fa\u53d6\u4ee3\uff0c\u4f7f\u5f97\u8be5\u5316\u5408\u7269\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\uff08pKa\u7ea6\u4e3a12.5\uff09\uff0c\u540c\u65f6\u7531\u4e8e\u7a7a\u95f4\u4f4d\u963b\u7684\u5b58\u5728\uff0c\u53c8\u5177\u5907\u4e00\u5b9a\u7684\u4eb2\u6838\u60f0\u6027\uff0c\u8fd9\u4f7f\u5176\u5728\u591a\u79cd\u6709\u673a\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u72ec\u7279\u7684\u4f18\u52bf\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c<\/th>\n<th>\u5355\u4f4d<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>115.17<\/td>\n<td>g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>80\u201383<\/td>\n<td>\u2103<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>190\u2013192<\/td>\n<td>\u2103\uff08\u51cf\u538b\uff09<\/td>\n<\/tr>\n<tr>\n<td>pKa<\/td>\n<td>~12.5<\/td>\n<td>&#8211;<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u6613\u6eb6\u4e8e\u6c34\u3001\u9187\u7c7b<\/td>\n<td>&#8211;<\/td>\n<\/tr>\n<tr>\n<td>\u78b1\u6027\u5f3a\u5ea6<\/td>\n<td>\u5f3a\u78b1<\/td>\n<td>&#8211;<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u56db\u7532\u57fa\u80cd\u7684\u8fd9\u4e9b\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u51b3\u5b9a\u4e86\u5b83\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u5e7f\u6cdb\u9002\u7528\u6027\u3002\u63a5\u4e0b\u6765\u6211\u4eec\u5c06\u5177\u4f53\u770b\u770b\u5b83\u662f\u5982\u4f55\u5f71\u54cd\u53cd\u5e94\u901f\u5ea6\u548c\u4ea7\u7269\u9009\u62e9\u6027\u7684\u3002<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u52a0\u901f\u53cd\u5e94\u7684\u79d8\u5bc6\u6b66\u5668\uff1a\u56db\u7532\u57fa\u80cd\u4e0e\u53cd\u5e94\u901f\u7387<\/h2>\n<p>\u5728\u8bb8\u591a\u6709\u673a\u53cd\u5e94\u4e2d\uff0c\u53cd\u5e94\u901f\u7387\u5f80\u5f80\u53d7\u9650\u4e8e\u5e95\u7269\u7684\u6d3b\u6027\u6216\u8005\u8fc7\u6e21\u6001\u7684\u5f62\u6210\u80fd\u5792\u3002\u800c\u56db\u7532\u57fa\u80cd\u4f5c\u4e3a\u78b1\u6027\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u901a\u8fc7\u53bb\u8d28\u5b50\u5316\u4f5c\u7528\u964d\u4f4e\u53cd\u5e94\u6d3b\u5316\u80fd\uff0c\u4ece\u800c\u52a0\u5feb\u53cd\u5e94\u8fdb\u7a0b\u3002<\/p>\n<h3>1. \u916f\u4ea4\u6362\u53cd\u5e94\u4e2d\u7684\u8868\u73b0<\/h3>\n<p>\u4ee5\u916f\u4ea4\u6362\u53cd\u5e94\u4e3a\u4f8b\uff0c\u56db\u7532\u57fa\u80cd\u53ef\u4ee5\u6709\u6548\u5730\u4fc3\u8fdb\u9187\u5bf9\u916f\u7684\u4eb2\u6838\u653b\u51fb\uff0c\u63d0\u5347\u53cd\u5e94\u6548\u7387\u3002\u76f8\u6bd4\u4f20\u7edf\u7684NaOH\u6216KOH\u50ac\u5316\u4f53\u7cfb\uff0cTMG\u4e0d\u4ec5\u907f\u514d\u4e86\u91d1\u5c5e\u76d0\u5e26\u6765\u7684\u526f\u4ea7\u7269\u95ee\u9898\uff0c\u8fd8\u80fd\u663e\u8457\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n<th>\u53cd\u5e94\u65f6\u95f4<\/th>\n<th>\u6536\u7387<\/th>\n<th>\u526f\u4ea7\u7269\u60c5\u51b5<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>NaOH<\/td>\n<td>6\u5c0f\u65f6<\/td>\n<td>82%<\/td>\n<td>\u591a<\/td>\n<\/tr>\n<tr>\n<td>KOH<\/td>\n<td>5\u5c0f\u65f6<\/td>\n<td>85%<\/td>\n<td>\u4e2d\u7b49<\/td>\n<\/tr>\n<tr>\n<td>\u56db\u7532\u57fa\u80cd<\/td>\n<td>2\u5c0f\u65f6<\/td>\n<td>94%<\/td>\n<td>\u5c11<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u53ef\u4ee5\u770b\u5230\uff0c\u4f7f\u7528\u56db\u7532\u57fa\u80cd\u540e\uff0c\u53cd\u5e94\u65f6\u95f4\u660e\u663e\u7f29\u77ed\uff0c\u4e14\u4ea7\u7269\u7eaf\u5ea6\u66f4\u9ad8\uff0c\u526f\u53cd\u5e94\u66f4\u5c11\u3002<\/p>\n<h3>2. \u7f29\u5408\u53cd\u5e94\u4e2d\u7684\u5e94\u7528<\/h3>\n<p>\u5728\u919b\u916e\u7f29\u5408\u53cd\u5e94\u4e2d\uff0c\u56db\u7532\u57fa\u80cd\u540c\u6837\u5c55\u73b0\u51fa\u4f18\u79c0\u7684\u50ac\u5316\u6027\u80fd\u3002\u5b83\u901a\u8fc7\u8131\u9664\u03b1-\u6c22\u7684\u65b9\u5f0f\u751f\u6210\u78b3\u8d1f\u79bb\u5b50\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u63a8\u52a8\u540e\u7eed\u52a0\u6210\u53cd\u5e94\u7684\u8fdb\u884c\u3002<\/p>\n<p>\u4f8b\u5982\uff0c\u5728\u82ef\u7532\u919b\u4e0e\u7684Aldol\u7f29\u5408\u4e2d\uff0c\u52a0\u5165\u9002\u91cfTMG\u53ef\u4f7f\u53cd\u5e94\u6e29\u5ea6\u4ece\u5e38\u89c4\u7684\u56de\u6d41\u72b6\u6001\u964d\u81f3\u5ba4\u6e29\uff0c\u4e14\u8f6c\u5316\u7387\u63d0\u9ad8\u7ea630%\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u7cbe\u51c6\u5236\u5bfc\u7684\u827a\u672f\uff1a\u56db\u7532\u57fa\u80cd\u4e0e\u4ea7\u7269\u9009\u62e9\u6027<\/h2>\n<p>\u5982\u679c\u8bf4\u53cd\u5e94\u901f\u7387\u662f\u201c\u5feb\u6162\u201d\u7684\u95ee\u9898\uff0c\u90a3\u4e48\u4ea7\u7269\u9009\u62e9\u6027\u5219\u662f\u201c\u65b9\u5411\u201d\u7684\u95ee\u9898\u3002\u56db\u7532\u57fa\u80cd\u4e4b\u6240\u4ee5\u5907\u53d7\u9752\u7750\uff0c\u9664\u4e86\u56e0\u4e3a\u5b83\u80fd\u63d0\u901f\uff0c\u66f4\u56e0\u4e3a\u5b83\u61c2\u5f97\u201c\u6311\u91cd\u70b9\u201d\u3002<\/p>\n<h3>1. \u533a\u57df\u9009\u62e9\u6027\u63a7\u5236<\/h3>\n<p>\u5728\u591a\u5b98\u80fd\u56e2\u5b58\u5728\u7684\u590d\u6742\u4f53\u7cfb\u4e2d\uff0c\u56db\u7532\u57fa\u80cd\u80fd\u591f\u901a\u8fc7\u5176\u78b1\u6027\u8c03\u8282\u53cd\u5e94\u8def\u5f84\uff0c\u4f18\u5148\u6fc0\u6d3b\u7279\u5b9a\u4f4d\u7f6e\u7684\u6d3b\u6027\u6c22\uff0c\u4ece\u800c\u5b9e\u73b0\u533a\u57df\u9009\u62e9\u6027\u7684\u6709\u6548\u63a7\u5236\u3002<\/p>\n<p>\u6bd4\u5982\u5728\u785d\u57fa\u82b3\u70c3\u8fd8\u539f\u53cd\u5e94\u4e2d\uff0c\u4f7f\u7528TMG\u4f5c\u4e3a\u6dfb\u52a0\u5242\u65f6\uff0c\u53ef\u4ee5\u9009\u62e9\u6027\u5730\u8fd8\u539f\u785d\u57fa\u4e3a\u6c28\u57fa\uff0c\u800c\u4e0d\u5f71\u54cd\u5176\u4ed6\u5982\u7fb0\u57fa\u3001\u916f\u57fa\u7b49\u654f\u611f\u5b98\u80fd\u56e2\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/2.jpg\" alt=\"\"><\/p>\n<p>\u6bd4\u5982\u5728\u785d\u57fa\u82b3\u70c3\u8fd8\u539f\u53cd\u5e94\u4e2d\uff0c\u4f7f\u7528TMG\u4f5c\u4e3a\u6dfb\u52a0\u5242\u65f6\uff0c\u53ef\u4ee5\u9009\u62e9\u6027\u5730\u8fd8\u539f\u785d\u57fa\u4e3a\u6c28\u57fa\uff0c\u800c\u4e0d\u5f71\u54cd\u5176\u4ed6\u5982\u7fb0\u57fa\u3001\u916f\u57fa\u7b49\u654f\u611f\u5b98\u80fd\u56e2\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6dfb\u52a0\u5242\u7c7b\u578b<\/th>\n<th>\u4e3b\u4ea7\u7269\u6bd4\u4f8b<\/th>\n<th>\u526f\u4ea7\u7269\u79cd\u7c7b<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u65e0\u6dfb\u52a0<\/td>\n<td>68%<\/td>\n<td>\u591a\u79cd\u8fd8\u539f\u526f\u4ea7\u7269<\/td>\n<\/tr>\n<tr>\n<td>TMG<\/td>\n<td>93%<\/td>\n<td>\u51e0\u4e4e\u65e0\u5e72\u6270<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u8fd9\u79cd\u9009\u62e9\u6027\u6765\u6e90\u4e8eTMG\u7684\u201c\u6e29\u548c\u201d\u78b1\u6027\uff0c\u5b83\u4e0d\u4f1a\u50cf\u5f3a\u78b1\u90a3\u6837\u5f15\u53d1\u4e00\u7cfb\u5217\u8fde\u9501\u53cd\u5e94\uff0c\u800c\u662f\u4e13\u6ce8\u4e8e\u5173\u952e\u6b65\u9aa4\u3002<\/p>\n<h3>2. \u5bf9\u6620\u9009\u62e9\u6027\u4e0e\u975e\u5bf9\u79f0\u5408\u6210<\/h3>\n<p>\u867d\u7136\u56db\u7532\u57fa\u80cd\u672c\u8eab\u4e0d\u5177\u5907\u624b\u6027\uff0c\u4f46\u5728\u67d0\u4e9b\u4e0d\u5bf9\u79f0\u50ac\u5316\u4f53\u7cfb\u4e2d\uff0c\u5b83\u53ef\u4ee5\u4f5c\u4e3a\u8f85\u52a9\u78b1\u53c2\u4e0e\u914d\u4f4d\u73af\u5883\u7684\u6784\u5efa\uff0c\u4ece\u800c\u95f4\u63a5\u5f71\u54cd\u624b\u6027\u4e2d\u5fc3\u7684\u5f62\u6210\u3002<\/p>\n<p>\u4f8b\u5982\u5728\u67d0\u4e9b\u812f\u6c28\u9178\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0Aldol\u53cd\u5e94\u4e2d\uff0c\u52a0\u5165TMG\u53ef\u4ee5\u589e\u5f3a\u50ac\u5316\u5242\u7684\u78b1\u6027\u73af\u5883\uff0c\u6539\u5584\u624b\u6027\u8bf1\u5bfc\u6548\u679c\uff0c\u4f7fee\u503c\uff08\u5bf9\u6620\u4f53\u8fc7\u91cf\uff09\u63d0\u9ad85%~10%\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u4ea7\u54c1\u53c2\u6570\u4e0e\u5de5\u4e1a\u5e94\u7528\u5bf9\u6bd4<\/h2>\n<p>\u4e3a\u4e86\u66f4\u597d\u5730\u7406\u89e3\u56db\u7532\u57fa\u80cd\u5728\u5b9e\u9645\u751f\u4ea7\u4e2d\u7684\u4ef7\u503c\uff0c\u6211\u4eec\u53ef\u4ee5\u5c06\u5176\u4e0e\u5176\u4ed6\u5e38\u7528\u78b1\u8fdb\u884c\u7cfb\u7edf\u6bd4\u8f83\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6027\u80fd\u6307\u6807<\/th>\n<th>\u56db\u7532\u57fa\u80cd<\/th>\n<th>DBU<\/th>\n<th>DABCO<\/th>\n<th>NaOH<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u78b1\u6027\u5f3a\u5f31<\/td>\n<td>\u5f3a<\/td>\n<td>\u6781\u5f3a<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u5f3a<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u8010\u70ed\u6027<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u4e00\u822c<\/td>\n<td>\u5dee<\/td>\n<td>\u5dee<\/td>\n<\/tr>\n<tr>\n<td>\u662f\u5426\u6b8b\u7559\u91d1\u5c5e<\/td>\n<td>\u5426<\/td>\n<td>\u5426<\/td>\n<td>\u5426<\/td>\n<td>\u662f<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u4e2d\u9ad8<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u5b89\u5168\u6027<\/td>\n<td>\u8f83\u9ad8<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u9ad8<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u8fd9\u5f20\u8868\u53ef\u4ee5\u770b\u51fa\uff0c\u5c3d\u7ba1TMG\u6210\u672c\u7565\u9ad8\uff0c\u4f46\u5176\u7efc\u5408\u6027\u80fd\u4f18\u8d8a\uff0c\u5c24\u5176\u9002\u5408\u5bf9\u4ea7\u7269\u7eaf\u5ea6\u8981\u6c42\u8f83\u9ad8\u7684\u7cbe\u7ec6\u5316\u5b66\u54c1\u548c\u533b\u836f\u4e2d\u95f4\u4f53\u5408\u6210\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u56db\u7532\u57fa\u80cd\u7684\u5e94\u7528\u5b9e\u4f8b\u4e0e\u524d\u666f\u5c55\u671b<\/h2>\n<h3>1. \u5728\u836f\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528<\/h3>\n<p>\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u666e\u53ca\uff0c\u56db\u7532\u57fa\u80cd\u5728\u5236\u836f\u9886\u57df\u7684\u5e94\u7528\u65e5\u76ca\u5e7f\u6cdb\u3002\u4f8b\u5982\u5728\u6297\u6291\u90c1\u836f\u5e15\u7f57\u897f\u6c40\uff08Paroxetine\uff09\u7684\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0cTMG\u88ab\u7528\u4f5c\u7f29\u5408\u53cd\u5e94\u7684\u78b1\u6027\u52a9\u5242\uff0c\u6210\u529f\u63d0\u9ad8\u4e86\u4ea7\u7387\u5e76\u51cf\u5c11\u4e86\u5e9f\u6c34\u5904\u7406\u538b\u529b\u3002<\/p>\n<h3>2. \u5728\u805a\u5408\u53cd\u5e94\u4e2d\u7684\u89d2\u8272<\/h3>\n<p>\u5728\u67d0\u4e9b\u9634\u79bb\u5b50\u805a\u5408\u53cd\u5e94\u4e2d\uff0c\u56db\u7532\u57fa\u80cd\u8fd8\u53ef\u4f5c\u4e3a\u94fe\u7ec8\u6b62\u5242\u6216\u94fe\u8f6c\u79fb\u8c03\u8282\u5242\uff0c\u7528\u4e8e\u63a7\u5236\u805a\u5408\u7269\u5206\u5b50\u91cf\u5206\u5e03\uff0c\u63d0\u5347\u6750\u6599\u6027\u80fd\u3002<\/p>\n<h3>3. \u672a\u6765\u53d1\u5c55\u65b9\u5411<\/h3>\n<p>\u968f\u7740\u4eba\u4eec\u5bf9\u53cd\u5e94\u8fc7\u7a0b\u7cbe\u7ec6\u5316\u63a7\u5236\u9700\u6c42\u7684\u63d0\u5347\uff0c\u56db\u7532\u57fa\u80cd\u7684\u7814\u7a76\u4e5f\u9010\u6b65\u5411\u529f\u80fd\u5316\u3001\u8d1f\u8f7d\u578b\u3001\u7eb3\u7c73\u5316\u65b9\u5411\u53d1\u5c55\u3002\u4f8b\u5982\uff0c\u5c06TMG\u56fa\u5b9a\u5728\u6811\u8102\u8f7d\u4f53\u4e0a\uff0c\u4e0d\u4ec5\u80fd\u91cd\u590d\u4f7f\u7528\uff0c\u8fd8\u80fd\u907f\u514d\u5176\u5728\u53cd\u5e94\u540e\u671f\u96be\u4ee5\u53bb\u9664\u7684\u95ee\u9898\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u7ed3\u8bed\uff1a\u4e00\u4f4d\u6c89\u9ed8\u7684\u5316\u5b66\u82f1\u96c4<\/h2>\n<p>\u56db\u7532\u57fa\u80cd\u6216\u8bb8\u4e0d\u50cf\u9176\u90a3\u6837\u201c\u806a\u660e\u201d\uff0c\u4e5f\u4e0d\u50cf\u8d35\u91d1\u5c5e\u90a3\u6837\u201c\u8d35\u6c14\u201d\uff0c\u4f46\u5b83\u4ee5\u5176\u72ec\u7279\u7684\u78b1\u6027\u9b45\u529b\u548c\u6e29\u548c\u7684\u6027\u683c\uff0c\u5728\u65e0\u6570\u6709\u673a\u53cd\u5e94\u4e2d\u9ed8\u9ed8\u626e\u6f14\u7740\u5173\u952e\u89d2\u8272\u3002\u5b83\u4e0d\u662f\u4e3b\u89d2\uff0c\u5374\u5e38\u5e38\u662f\u51b3\u5b9a\u6210\u8d25\u7684\u5173\u952e\uff1b\u5b83\u4e0d\u55a7\u54d7\uff0c\u5374\u603b\u80fd\u5728\u5173\u952e\u65f6\u523b\u633a\u8eab\u800c\u51fa\u3002<\/p>\n<p>\u6b63\u5982\u4e00\u4f4d\u8001\u5316\u5b66\u5bb6\u66fe\u8bf4\uff1a\u201c\u597d\u7684\u50ac\u5316\u5242\uff0c\u4e0d\u662f\u8ba9\u4f60\u770b\u5230\u5b83\u7684\u5b58\u5728\uff0c\u800c\u662f\u8ba9\u4f60\u770b\u4e0d\u5230\u5b83\uff0c\u5374\u79bb\u4e0d\u5f00\u5b83\u3002\u201d<\/p>\n<p>\u4ee5\u4e0b\u662f\u4e00\u4e9b\u56fd\u5185\u5916\u5173\u4e8e\u56db\u7532\u57fa\u80cd\u7814\u7a76\u7684\u91cd\u8981\u6587\u732e\u63a8\u8350\uff0c\u4f9b\u6709\u5174\u8da3\u7684\u670b\u53cb\u8fdb\u4e00\u6b65\u67e5\u9605\uff1a<\/p>\n<h3>\u56fd\u5185\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>\u674e\u660e, \u738b\u534e. \u56db\u7532\u57fa\u80cd\u50ac\u5316\u916f\u4ea4\u6362\u53cd\u5e94\u7684\u7814\u7a76\u8fdb\u5c55[J]. \u7cbe\u7ec6\u5316\u5de5, 2020, 37(4): 65-70.<\/li>\n<li>\u5f20\u4f1f, \u5218\u6653\u4e1c. TMG\u5728\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\u7684\u5e94\u7528\u7efc\u8ff0[J]. \u6709\u673a\u5316\u5b66, 2019, 39(11): 3125-3132.<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>Smith, M. B., &amp; March, J. <em>March&#8217;s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure.<\/em> Wiley, 2007.<\/li>\n<li>Corey, E. J., &amp; Cheng, X. M. <em>The Logic of Chemical Synthesis.<\/em> Wiley, 1989.<\/li>\n<li>Zhang, Y., et al. &quot;Tetramethylguanidine as a versatile organocatalyst in organic transformations.&quot; <em>Organic &amp; Biomolecular Chemistry<\/em>, 2021, 19(12), 2655-2668.<\/li>\n<li>Enders, D., et al. &quot;Organocatalysis by guanidines: from small molecules to supported catalysts.&quot; <em>Advanced Synthesis &amp; Catalysis<\/em>, 2006, 348(14), 1895-1904.<\/li>\n<\/ol>\n<p>\u613f\u6211\u4eec\u5728\u672a\u6765\u7684\u79d1\u7814\u4e4b\u8def\u4e0a\uff0c\u7ee7\u7eed\u53d1\u73b0\u66f4\u591a\u8fd9\u6837\u201c\u4f4e\u8c03\u6709\u5185\u6db5\u201d\u7684\u5316\u5b66\u7cbe\u7075\u3002<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n<ul>\n<li>\n<h3>NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-14 \u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5bc6\u5c01\u80f6\u548c\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-15 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6bd4A-14\u6d3b\u6027\u4f4e\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-16 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\u548c\u4e00\u5b9a\u7684\u8010\u6c34\u89e3\u6027\uff0c\u7ec4\u5408\u6599\u50a8\u5b58\u65f6\u95f4\u957f\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-128 \u9002\u7528\u4e8e\u805a\u6c28\u916f\u53cc\u7ec4\u4efd\u5feb\u901f\u56fa\u5316\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5728\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u50ac\u5316\u6d3b\u6027\u5f3a\uff0c\u7279\u522b\u9002\u5408\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-129 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u5ef6\u8fdf\u6548\u679c\uff0c\u4e0e\u6c34\u7684\u7a33\u5b9a\u6027\u8f83\u5f3a\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-138 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u826f\u597d\u7684\u6d41\u52a8\u6027\u548c\u8010\u6c34\u89e3\u6027\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-154 \u9002\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-159 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u53ef\u7528\u6765\u66ff\u4ee3A-14\uff0c\u6dfb\u52a0\u91cf\u4e3aA-14\u768450-60%\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT MB20 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u66ff\u4ee3\u8f6f\u8d28\u5757\u72b6\u6ce1\u6cab\u3001\u9ad8\u5bc6\u5ea6\u8f6f\u8d28\u6ce1\u6cab\u3001\u55b7\u6d82\u6ce1\u6cab\u3001\u5fae\u5b54\u6ce1\u6cab\u4ee5\u53ca\u786c\u8d28\u6ce1\u6cab\u4f53\u7cfb\u4e2d\u7684\u9521\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6d3b\u6027\u6bd4\u6709\u673a\u9521\u76f8\u5bf9\u8f83\u4f4e\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT T-12 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